Principal trends in chemistry of amidinate complexes of main-group and transition elements

被引：0

作者：

Kissounko, D. A. ^{[1
]}

Zabalov, M. V.

Brusova, G. P.

Lemenovskii, D. A.

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

USPEKHI KHIMII | 2006年 / 75卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Main lines of investigations of complexes containing amidinate ligands are analysed and their role in modern organometallic chemistry is shown. The nature of the element-amidinate ligand bond is considered based on X-ray structural data and quantum-chemical calculations. The methods for the synthesis of amidinate complexes of elements of Groups 1 to 15 of the Periodic Table and their chemical properties are described. The problems related to the use of such compounds in organic synthesis and as olefin polymerisation catalysts are discussed in detail. Prospects in this field of chemistry are presented.

引用

页码：395 / 421

页数：27

共 154 条

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