[CuCl(C12H9N2O5)(C12H10N2O5)(H2O)]

被引：4

作者：

Ruíz, M

Ortiz, R

Perelló, L

Castiñeiras, A

机构：

[1] Univ Valencia, Fac Farm, Dept Quim Inorgan, E-46100 Burjassot, Valencia, Spain

[2] Univ Santiago Compostela, Fac Farm, Dept Quim Inorgan, E-15706 Santiago, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199001122

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, aquachloro(1-ethyl-1,4-dihydro-4-oxo-1,3-dioxolo [4,5-g]cinnoline-3-carboxylato-O-3,O-4)-(1-ethyl-1,4-dihydro-4-oxo-1,3-dioxolo[4,5-g]cinnoline-3- carboxylic acid-O-3, O-4)copper(II), the Cu-II ion adopts a tetragonally distorted octahedral geometry. In the equatorial plane, the Cu-II ion is coordinated to two O atoms (O-keto and O-carboxylate) of one cinoxacinate ligand, and to two O atoms (O-keto and O-carboxylic) of one cinoxacin molecule. The apical positions are occupied by one O atom from the water molecule and one Cl- ion, resulting in a CuClO5 chromophore.

引用

收藏

页码：878 / 880

页数：3

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