Supramolecular aggregation of hexameric water clusters into a 2D water polymer containing (H2O)18 holes

被引：72

作者：

Carballo, R ^{[1
]}

Covelo, B ^{[1
]}

Fernández-Hermida, N ^{[1
]}

García-Martínez, E ^{[1
]}

Lago, AB ^{[1
]}

Vázquez, M ^{[1
]}

Vázquez-López, EM ^{[1
]}

机构：

[1] Univ Vigo, Fac Quim, Dept Quim Inorgan, Vigo 36310, Spain

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 03期

关键词：

D O I：

10.1021/cg0505923

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein a novel infinite two-dimensional water morphology, found in a metallo-organic host, made tip of discrete cyclic water hexamers and which contains large circular holes defined by 18 molecules of water.

引用

页码：629 / 631

页数：3

共 55 条

[1]

[Anonymous], 1970, CHEM PHYS ICE

[2] A well-resolved ice-like (H2O)8 cluster in an organic supramolecular complex [J].

Atwood, JL ;

Barbour, LJ ;

Ness, TJ ;

Raston, CL ;

Raston, PL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (29) :7192-7193

[3] Effect of H2SO4 and alkali metal SO42-/HSO4- salt solutions on surface water molecules using sum frequency generation [J].

Baldelli, S ;

Schnitzer, C ;

Campbell, DJ ;

Shultz, MJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (14) :2789-2795

[4] Characterization of a well resolved supramolecular ice-like (H2O)10 cluster in the solid state [J].

Barbour, LJ ;

Orr, GW ;

Atwood, JL .

CHEMICAL COMMUNICATIONS, 2000, (10) :859-860

[5] An intermolecular (H2O)10 cluster in a solid-state supramolecular complex [J].

Barbour, LJ ;

Orr, GW ;

Atwood, JL .

NATURE, 1998, 393 (6686) :671-673

[6] Synthesis and crystallographic characterization of an octameric water complex, (H2O)8 [J].

Blanton, WB ;

Gordon-Wylie, SW ;

Clark, GR ;

Jordan, KD ;

Wood, JT ;

Geiser, U ;

Collins, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) :3551-3552

[7] One-dimensional fluorescent stacking structure based on zinc mixed-complex salt encapsulated within an 'ice-like' three-dimensional hydrogen-bonded water network [J].

Carballo, R ;

Covelo, B ;

Lodeiro, C ;

Vázquez-López, EM .

CRYSTENGCOMM, 2005, 7 :294-296

[8]

Custelcean R, 2000, ANGEW CHEM INT EDIT, V39, P3094, DOI 10.1002/1521-3773(20000901)39:17<3094::AID-ANIE3094>3.0.CO

[9]

2-P

[10]

Eisenberg D., 1969, STRUCTURE PROPERTIES

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