Ultrasonic Degradation of Fuchsin Basic in Aqueous Solution: Effects of Operating Parameters and Additives

被引:13
|
作者
Lan, Rui-Jia [1 ,2 ]
Li, Ji-Tai [1 ]
Chen, Bao-Hua [1 ]
机构
[1] Hebei Univ, Coll Chem & Environm Sci, Key Lab Analyt Sci & Technol Hebei Prov, Baoding 071002, Peoples R China
[2] Langfang Teachers Coll, Fac Chem & Mat Sci, Langfang 065000, Peoples R China
关键词
SONOCHEMICAL DEGRADATION; SONOCATALYTIC DEGRADATION; ORGANIC-COMPOUNDS; METHYLENE-BLUE; ADSORPTION; SONOLYSIS; WATER; DESTRUCTION; TEMPERATURE; COMBINATION;
D O I
10.1155/2013/893131
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ultrasonic degradation is one of the recent advanced oxidation processes (AOPs) and proven to be effective for removing low-concentration organic pollutants from aqueous solutions. In this study, removal of fuchsin basic from aqueous solutions by ultrasound was investigated. The effects of operating parameters such as ultrasound power (200 W-500 W), initial pH (3-6.5), and temperature (15, 22, 35, and 60 degrees C) on the ultrasonic degradation were studied. The degradation of fuchsin under ultrasound irradiation basic was found to obey pseudo first-order reaction kinetics. Addition of catalyst Fe(II) had a markedly positive effect on degradation. 84.1% extent of degradation was achieved at initial dye concentration 10 mu mol L-1, ultrasound power 400 W, ultrasound frequency 25 kHz, dosage of Fe(II) 4 mg L-1, initial pH 6.5, and temperature 22 degrees C. But addition of heterogeneous catalyst TiO2 affected degradation slightly. Addition of radical scavenger suppressed fuchsin basic degradation significantly.
引用
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页数:7
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