Square-wave voltammetric determination of paraquat using a glassy carbon electrode modified with multiwalled carbon nanotubes within a dihexadecylhydrogenphosphate (DHP) film

A simple, highly sensitive square-wave voltammetric method is reported for the sensing of paraquat (PQ) in natural water samples. A glassy carbon electrode modified with functionalized multiwalled carbon nanotubes (MWCNTs) immobilized within a Dihexadecylhydrogenphosphate (DHP) film was prepared and characterized with cyclic, differential-pulse and square-wave voltammetry. The modified electrode was found to exhibit a remarkably enhanced electro-activity toward the sensing of paraquat. Under optimum experimental conditions, using square wave voltammetry, the sensing of paraquat is achievable over the concentration range from 5.0 x 10(-8) to 1.5 x 10(-6) mol L-1 with a detection limit (3 sigma) of 1.0 x 10(-8) mol L-1. The protocol is explored toward potential interferents and is applied for the analysis of paraquat in natural waters with the results agreeing with independently verified HPLC at a 95% confidence level. (C) 2013 Elsevier B.V. All rights reserved.