Enhanced fluid flow through nanoscale carbon pipes

被引:309
作者
Whitby, Max [1 ]
Cagnon, Laurent [2 ,3 ]
Thanou, Maya [1 ]
Quirke, Nick [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Univ Grenoble 1, F-38042 Grenoble 9, France
[3] CNRS, Inst Neel, F-38042 Grenoble 9, France
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1021/nl080705f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recent experimental and theoretical studies demonstrate that pressure driven flow of fluids through nanoscale (d < 10 nm) carbon pores occurs 4 to 5 orders of magnitude faster than predicted by extrapolation from conventional theory. Here, we report experimental results for flow of water, ethanol, and decane through carbon nanopipes with larger inner diameters (43 +/- 3 nm) than previously investigated. We find enhanced transport up to 45 times theoretical predictions. In contrast to previous work, in our systems, decane flows faster than water. These nanopipes were composed of amorphous carbon deposited from ethylene vapor in alumina templates using a single step fabrication process.
引用
收藏
页码:2632 / 2637
页数:6
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