Recent advances in porphyrinic metal-organic frameworks: materials design, synthetic strategies, and emerging applications

被引：125

作者：

Burnett, Brandon J. ^{[1
]}

Barron, Paul M. ^{[1
]}

Choe, Wonyoung ^{[1
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 11期

关键词：

SINGLE-CRYSTAL TRANSFORMATIONS; COORDINATION POLYMERS; COMPLEXES; RESTRICTION; CENTERS; CONSTRUCTION; ADSORPTION; SERIES; METALLOLIGANDS; NETWORKS;

D O I：

10.1039/c2ce06692k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This highlight presents a review of porphyrin paddlewheel frameworks (PPFs) created using porphyrin metalloligands and paddlewheel secondary building units. The combination of these two components, along with dipyridyl pillaring linkers, results in the assembly of 25 PPFs. We describe the topology control exhibited in this series by considering the preferred coordination geometry of the porphyrin building blocks, the length and steric effects of the pillars, and the use of sequential self-assembly. These PPFs and related porphyrinic metal-organic frameworks are emerging as important materials for applications such as heterogeneous catalysis, gas storage, and light harvesting.

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页码：3839 / 3846

页数：8

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