Recyclable palladium catalyst for facile synthesis of imines from benzyl alcohols and nitroarenes

被引：32

作者：

Chen, Jing ^{[1
]}

Huang, Shijun ^{[1
]}

Lin, Jin ^{[1
]}

Su, Weiping ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

APPLIED CATALYSIS A-GENERAL | 2014年 / 470卷

关键词：

Imine synthesis; One-pot reaction; Palladium; Heterogeneous catalysis; Nitrobenzene; POT PHOTOCATALYTIC SYNTHESIS; AMINE FORMATION; N-ALKYLATION; DEHYDROGENATION; RUTHENIUM; HYDROTALCITE;

D O I：

10.1016/j.apcata.2013.10.033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using a supported palladium catalytic system, the reaction of nitroarenes with benzyl alcohols occurred smoothly via hydrogen transfer to produce imines in an atom-economical manner. The palladium species were dispersed well on hydrotalcite (HT) support and palladium nanoparticles with size of about 3.5 nm were formed during reaction. Both of the small size of palladium nanoparticles and the rich hydroxyl groups on HT surface enhanced the catalytic performance of Pd/HT. The catalytic system is recyclable and amenable to a variety of aromatic alcohols and nitro compounds. (C) 2013 Elsevier B.V. All rights reserved.

引用

收藏

页码：1 / 7

页数：7

相关论文

共 28 条

[1] Impregnated Ruthenium on Magnetite as a Recyclable Catalyst for the N-Alkylation of Amines, Sulfonamides, Sulfinamides, and Nitroarenes Using Alcohols as Electrophiles by a Hydrogen Autotransfer Process [J].

Cano, Rafael ;

Ramon, Diego J. ;

Yus, Miguel .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (14) :5547-5557

[2] Oxidant-Free Dehydrogenation of Alcohols over Hydrotalcite-Supported Palladium Catalysts [J].

Chen Jing ;

Zhang Qinghong ;

Fang Wenhao ;

Wang Ye ;

Wan Huilin .

CHINESE JOURNAL OF CATALYSIS, 2010, 31 (08) :1061-1070

[3] A Bifunctional Pd/MgO Solid Catalyst for the One-Pot Selective N-Monoalkylation of Amines with Alcohols [J].

Corma, Avelino ;

Rodenas, Tania ;

Sabater, Maria J. .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (01) :254-260

[4] Ruthenium-Catalyzed Nitro and Nitrile Compounds Coupling with Alcohols: Alternative Route for N-Substituted Amine Synthesis [J].

Cui, Xinjiang ;

Zhang, Yan ;

Shi, Feng ;

Deng, Youquan .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (09) :2587-2591

[5] Reconstructed hydrotalcite as a highly active heterogeneous base catalyst for carbon-carbon bond formations in the presence of water [J].

Ebitani, Kohki ;

Motokura, Ken ;

Mori, Kohsuke ;

Mizugaki, Tomoo ;

Kaneda, Kiyotomi .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (15) :5440-5447

[6] Iminium catalysis [J].

Erkkila, Anniina ;

Majander, Inkeri ;

Pihko, Petri M. .

CHEMICAL REVIEWS, 2007, 107 (12) :5416-5470

[7] Hydrotalcite-Supported Gold Catalyst for the Oxidant-Free Dehydrogenation of Benzyl Alcohol: Studies on Support and Gold Size Effects [J].

Fang, Wenhao ;

Chen, Jiashu ;

Zhang, Qinghong ;

Deng, Weiping ;

Wang, Ye .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (04) :1247-1256

[8] Ruthenium-Catalyzed Tertiary Amine Formation from Nitroarenes and Alcohols [J].

Feng, Chao ;

Liu, Yong ;

Peng, Shengming ;

Shuai, Qi ;

Deng, Guojun ;

Li, Chao-Jun .

ORGANIC LETTERS, 2010, 12 (21) :4888-4891

[9] Acceptorless Dehydrogenation of Alcohols: Perspectives for Synthesis and H2 Storage [J].

Friedrich, Anja ;

Schneider, Sven .

CHEMCATCHEM, 2009, 1 (01) :72-73

[10] Recent Progress in Lewis Base Activation and Control of Stereoselectivity in the Additions of Trimethylsilyl Nucleophiles [J].

Gawronski, Jacek ;

Wascinska, Natalia ;

Gajewy, Jadwiga .

CHEMICAL REVIEWS, 2008, 108 (12) :5227-5252