High-pressure phase behavior of systems with ionic liquids: II. The binary system carbon dioxide+1-ethyl-3-methylimidazolium hexafluorophosphate

被引：166
作者：
Shariati, A [1 ]
Peters, CJ [1 ]
机构：
[1] Delft Univ Technol, Fac Sci Appl, Lab Appl Thermodynam & Phase Equilibria, NL-2628 BL Delft, Netherlands
来源：
JOURNAL OF SUPERCRITICAL FLUIDS | 2004年 / 29卷 / 1-2期
关键词：
1-ethyl-3-methylimidazolium hexafluorophosphate; carbon dioxide; phase behavior; ionic liquid;
D O I：
10.1016/S0896-8446(03)00032-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this work the phase behavior of a binary mixture consisting of a supercritical fluid and an imidazolium-based ionic liquid (IL) was studied experimentally. Carbon dioxide was selected as the supercritical fluid and 1-ethyl-3-methytimidazolium hexafluorophosphate was considered as the IL. A synthetic method was used to measure vapor-liquid boundaries. Results are reported for carbon dioxide concentrations ranging from 10.4 up to 61.9 mol%, and within temperature and pressure ranges of 308.14-366.03 K and 1.49-97. 10 MPa, respectively. Also, the experimental results obtained in this work were compared with other available binary systems of supercritical fluid + IL. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：43 / 48
页数：6
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