Linker extension through hard-soft selective metal coordination for the construction of a non-rigid metal-organic framework

被引：25
作者：
Wei ZhangWen [1 ]
Yuan DaQiang [2 ]
Zhao XiaoLiang [3 ]
Sun DaoFeng [3 ]
Zhou Hong-Cai [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
[3] Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2013年 / 56卷 / 04期
基金：
美国国家科学基金会;
关键词：
MOF; linker extension; copper (I); HYDROGEN STORAGE; SOLVOTHERMAL SYNTHESIS; DESIGN; CATALYSIS; POLYMER; PORES; TRANSFORMATION; STABILIZATION; LUMINESCENCE; SEPARATION;
D O I：
10.1007/s11426-013-4851-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A metal-organic framework (MOF) has been obtained by using a linker extension strategy. Three di-anions of 4-(3,5-dimethyl-1H-pyrazol-4-yl)-benzoic acid coordinate to three Cu(I) ions forming an extended trigonal planar ligand, which links three di-copper paddlewheel units giving rise to a Pt3O4 net.
引用
收藏
页码：418 / 422
页数：5
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