Formulation and phase behavior study of a nonionic triglyceride microemulsion to increase hydrocarbon production

被引:20
作者
Jeirani, Z. [1 ]
Jan, B. Mohamed [1 ]
Ali, B. Si [1 ]
Noor, I. M. [1 ]
See, C. H. [2 ]
Saphanuchart, W. [2 ]
机构
[1] Univ Malaya, Dept Chem Engn, Fac Engn, Kuala Lumpur 50603, Malaysia
[2] BCI Chem Corp Sdn Bhd, Seri Kembangan 43300, Selangor Darul, Malaysia
关键词
Microemulsion; Enhanced oil recovery; Chemical flooding; Palm oil; Triglyceride; SOLUBILIZATION; SURFACTANT; OIL; WATER;
D O I
10.1016/j.indcrop.2012.07.004
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
It is no secret that during microemulsion flooding, the oil entrapped in rock pores can be easily removed when a new Winsor Type III microemulsion is formed in situ. Formulation of an efficient microemulsion in tertiary oil recovery requires good understanding of its phase behavior. This paper presents the phase behavior study of a triglyceride microemulsion before and after n-octane solubilization in formulating an efficient triglyceride microemulsion. The effects of solubilized oil as co-oil, salinity, surfactant concentration and co-surfactant concentration on the phase behavior of a triglyceride microemulsion were investigated. The optimized aqueous phase composition of the triglyceride microemulsion was adjusted at 1 wt% alkyl polyglycosides, 3 wt% glyceryl monooleate, 3 wt% sodium chloride, and 93 wt% de-ionized water. It is concluded that this condition represents the widest range and the maximum volume of Winsor Type III microemulsion that can be achieved for the triglyceride microemulsion after fluid injection. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:15 / 24
页数:10
相关论文
共 34 条
  • [1] Linker-modified microemulsions for a variety of oils and surfactants
    Acosta, E
    Do Mai, P
    Harwell, JH
    Sabatini, DA
    [J]. JOURNAL OF SURFACTANTS AND DETERGENTS, 2003, 6 (04) : 353 - 363
  • [2] Formulating chlorinated hydrocarbon microemulsions using linker molecules
    Acosta, E
    Tran, S
    Uchiyama, H
    Sabatini, DA
    Harwell, JH
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (21) : 4618 - 4624
  • [3] [Anonymous], 1998, SPE TXB SERIES
  • [4] Bouassida M, 2006, PROC 2 INT C PROBLEM, P1
  • [5] Phase behavior and microstructure of C12E5 nonionic microemulsions with chlorinated oils
    Deen, G. Roshan
    Pedersen, Jan Skov
    [J]. LANGMUIR, 2008, 24 (07) : 3111 - 3117
  • [6] Environmentally Friendly Vegetable Oil Microemulsions Using Extended Surfactants and Linkers
    Do, Linh D.
    Withayyapayanon, Anuradee
    Harwell, Jeffrey H.
    Sabatini, David A.
    [J]. JOURNAL OF SURFACTANTS AND DETERGENTS, 2009, 12 (02) : 91 - 99
  • [7] Triacylglycerol microemulsions stabilized by alkyl ethoxylate surfactants - A basic study - Phase behavior, interfacial tension and microstructure
    Engelskirchen, S.
    Elsner, N.
    Sottmann, T.
    Strey, R.
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 312 (01) : 114 - 121
  • [8] Formulation and characterization of microemulsions based on mixed nonionic surfactants and peppermint oil
    Fanun, Monzer
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 343 (02) : 496 - 503
  • [9] IMPROVING SOLUBILIZATION IN MICROEMULSIONS WITH ADDITIVES .1. THE LIPOPHILIC LINKER ROLE
    GRACIAA, A
    LACHAISE, J
    CUCUPHAT, C
    BOURREL, M
    SALAGER, JL
    [J]. LANGMUIR, 1993, 9 (03) : 669 - 672
  • [10] Microemulsification of triglyceride sebum and the role of interfacial structure on bicontinuous phase behavior
    Huang, L
    Lips, A
    Co, CC
    [J]. LANGMUIR, 2004, 20 (09) : 3559 - 3563