Orientations of polyoxometalate anions on gold nanoparticles

被引：18

作者：

Sharet, Shelly ^{[1
]}

Sandars, Ella ^{[1
]}

Wang, Yifeng ^{[1
]}

Zeiri, Offer ^{[1
]}

Neyman, Alevtina ^{[1
]}

Meshi, Louisa ^{[2
,3
]}

Weinstock, Ira A. ^{[1
,3
]}

机构：

[1] Ben Gurion Univ Negev, Dept Chem, Beer Sheva, Israel

[2] Ben Gurion Univ Negev, Dept Mat Engn, IL-84105 Beer Sheva, Israel

[3] Ben Gurion Univ Negev, Ilse Katz Inst Nanoscale Sci & Technol, IL-84105 Beer Sheva, Israel

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 33期

关键词：

METAL NANOPARTICLES; SURFACES; NANOCLUSTERS; DERIVATIVES; LACUNARY;

D O I：

10.1039/c2dt30592e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cryogenic transmission electron microscopy of polyoxometalate-protected gold nanoparticles reveals that the Preyssler ion, [NaP5W30O110](14-), lies "face down" with its C-5 axis perpendicular to the gold surface, while the Finke-Droege ion, [P4W30Zn4(H2O)(2)O-112](16-), is "tilted", with its long axis close to 60 degrees from the normal to the surface.

引用

页码：9849 / 9851

页数：3

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