Synthesis of New Rhodacarborane [3,3-(1',5'-COD)-8-PrNH=C(Et)NH-3,1,2-RhC2B9H10]

被引：12
|
作者：
Stogniy, M. Yu [1 ]
Bogdanova, E., V [1 ]
Anufriev, S. A. [1 ]
Sivaev, I. B. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2022年 / 67卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
polyhedral boron hydrides; carboranes; nido-carborane; amidines; semi-sandwich complexes; rhodium; TRANSITION-METAL-COMPLEXES; CLOSO-DECABORATE ANION; BORON CLUSTER ANIONS; MOLECULAR-STRUCTURE; DERIVATIVES; REACTIVITY; CHEMISTRY; CATALYSIS; METALLACARBORANES; CRYSTAL;
D O I：
10.1134/S0036023622600848
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
It has been established that the complexation of the amidine derivative of nido-carborane 10-PrNHC(Et)=HN-7,8-C2B9H11 with (1,5-cyclooctadiene)rhodium(I) chloride dimer [(COD)RhCl](2) in tetrahydrofuran in the presence of potassium tert-butoxide as a base leads to a new 18-electron rhodium(I) complex of the semi-sandwich type, in which the dicarbollide ligand chelates the metal by the eta(5)-type. The structure of the resulting complex has been confirmed by NMR, IR, and UV spectroscopy, as well as mass spectrometry. The synthesized complex is the first example of a rhodium(I) complex based on a symmetrically substituted nido-carborane derivative with a boron-nitrogen bond.
引用
收藏
页码：1537 / 1544
页数：8
相关论文
共 50 条
  • [1] Synthesis of New Rhodacarborane [3,3-(1',5'-COD)-8-PrNH=C(Et)NH-3,1,2-RhC2B9H10]
    M. Yu. Stogniy
    E. V. Bogdanova
    S. A. Anufriev
    I. B. Sivaev
    Russian Journal of Inorganic Chemistry, 2022, 67 : 1537 - 1544
  • [2] Different reactivity of cyclooctadiene complexes 3,3-(cod)-8-SMe2-closo-3,1,2-RhC2B9H10 and 1,8-Me2-2,2-(cod)-11-SMe2-2,1,8-closo-RhC2B9H8 toward iodine
    Vinogradov, Mikhail M.
    Nelyubina, Yulia V.
    Ikonnikov, Nikolay S.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 867 : 224 - 227
  • [3] Cationic iridacarboranes [3-(arene)-3,1,2-IrC2B9H11]+ and [3-(MeCN)3-3,1,2-IrC2B9H11]+: Synthesis, reactivity, and bonding. Catalysis of oxidative coupling of benzoic acid with alkynes
    Loginov, Dmitry A.
    Belova, Alena O.
    Vologzhanina, Anna V.
    Kudinov, Alexander R.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 793 : 232 - 240
  • [4] (Cyclopentadienyl)metalladicarbollides 3-(η-C5R5)-3,1,2-MC2B9H11(M = Co, Rh, Ir): Synthesis, electrochemistry, and bonding
    Loginov, Dmitry A.
    Starikova, Zoya A.
    Corsini, Maddalena
    Zanello, Piero
    Kudinov, Alexander R.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 747 : 69 - 75
  • [5] Synthesis of 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10 by cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with C6H5ZnCl catalyzed by palladium complexes
    L. I. Zakharkin
    G. G. Zhigareva
    E. V. Balagurova
    Russian Chemical Bulletin, 1998, 47 : 1222 - 1223
  • [6] Synthesis of 9-C6H5-3-(π-C6H5)-3,1,2-CoC2B9H10 by cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with C6H5ZnCl catalyzed by palladium complexes
    Zakharkin, LI
    Zhigareva, GG
    Balagurova, EV
    RUSSIAN CHEMICAL BULLETIN, 1998, 47 (06) : 1222 - 1223
  • [7] Sterically encumbered charge-compensated carbaboranes: Synthesis and reactivity - Molecular structures of 7-Ph-11-SMe2-7,8-nido-C2B9H10 and 1-Ph-3,3-(CO2-7-SMe)(2)-3,1,2-closo-RhC2B9H8
    Rosair, GM
    Welch, AJ
    Weller, AS
    Zahn, SK
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 536 (1-2) : 299 - 308
  • [8] Fluorosubstituted rhodacarboranes 3,3-(R3P)(2)-3-H-3,1,2-RhC2B9H11-nFn (n=1, 2, 4): Synthesis, molecular structure, and catalytic properties in hydrosilylation of styrene and phenylacetylene
    Lebedev, VN
    Balagurova, EV
    Dolgushin, FM
    Yanovskii, AI
    Zakharkin, LI
    RUSSIAN CHEMICAL BULLETIN, 1997, 46 (03) : 550 - 558
  • [9] Charge-compensated carbarhodaboranes.: Synthesis and molecular structures of 3-L-3,3-(I)2-4-SMe2-3,1,2-closo-RhC2B9H10, L = CO or PPh3
    Boyd, ASF
    Rosair, GM
    Tiarks, FBH
    Weller, AS
    Zahn, SK
    Welch, AJ
    POLYHEDRON, 1998, 17 (16) : 2627 - 2632
  • [10] The synthesis of 3,3,3-(Ph2P)3CH-closo-3,1,2-RuC2B9H11, a novel ruthenacarborane complex with a chelate tridentate ligand
    Kaltenberg, A. A.
    Penkal', A. M.
    Somov, N., V
    Grishin, I. D.
    RUSSIAN CHEMICAL BULLETIN, 2019, 68 (04) : 770 - 776
12345