Highly efficient La0.8Sr0.2MnO3-δ - Ce0.9Gd0.1O1.95 nanocomposite cathodes for solid oxide fuel cells

被引:18
|
作者
dos Santos-Gomez, L. [1 ]
Zamudio-Garcia, J. [1 ]
Porras-Vazquez, J. M. [1 ]
Losilla, E. R. [1 ]
Marrero-Lopez, D. [2 ]
机构
[1] Univ Malaga, Dept Quim Inorgan Cristalog & Mineral, E-29071 Malaga, Spain
[2] Univ Malaga, Dept Fis Aplicada 1, Lab Mat & Superficie, E-29071 Malaga, Spain
关键词
Solid Oxide Fuel Cells; La0.8Sr0.2MnO3-delta; CeO2; Spray-pyrolysis; SPRAY-PYROLYSIS; COMPOSITE CATHODES; ELECTROCHEMICAL PERFORMANCE; RATIONAL DESIGN; TEMPERATURE; MICROSTRUCTURE; ELECTRODES; DEPOSITION; FILMS; OPTIMIZATION;
D O I
10.1016/j.ceramint.2017.12.089
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
La0.8Sr0.2MnO3-delta-Ce0.9Gd0.1O1.95 (LSM-CGO) nanostructured cathodes are successfully prepared in a single process by a chemical spray -pyrolysis deposition method. The cathode is composed of nanometric particles of approximately 15 nm of diameter, providing high triple-phase boundary sites for the oxygen reduction reactions. A low polarization resistance of 0.046 Omega cm(2) is obtained at 700 degrees C, which is comparable to the most efficient cobaltite-based perovskite cathodes. A NiO-YSZ anode supported fuel cell with the nanostructured cathode generates a power output of 1.4 W cm(-2) at 800 degrees C, significantly higher than 0.75 W cm(-2) for a cell with conventional LSM-CGO cathode. The results suggest that this is a promising strategy to achieve high efficiency electrodes for Solid Oxide Fuel Cells in a single preparation step, simplifying notably the fabrication process compared to traditional methods.
引用
收藏
页码:4961 / 4966
页数:6
相关论文
共 50 条
  • [21] In Situ Synthesized La0.6Sr0.4Co0.2Fe0.8O3-δ-Gd0.1Ce0.9O1.95 Article Nanocomposite Cathodes via a Modified Sol-Gel Process for Intermediate Temperature Solid Oxide Fuel Cells
    Joh, Dong Woo
    Cha, Areum
    Park, Jeong Hwa
    Kim, Kyeong Joon
    Bae, Kyung Taek
    Kim, Doyeub
    Choi, Young Ki
    An, Hyegsoon
    Shin, Ji Su
    Yoon, Kyung Joong
    Lee, Kang Taek
    ACS APPLIED NANO MATERIALS, 2018, 1 (06): : 2934 - 2942
  • [22] One dimensional La0.8Sr0.2Co0.2Fe0.8O3-δ/Ce0.8Gd0.2O1.9 nanocomposite cathodes for intermediate temperature solid oxide fuel cells
    Zhao, Erqing
    Jia, Zheng
    Zhao, Li
    Xiong, Yueping
    Sun, Chunwen
    Brito, Manuel E.
    JOURNAL OF POWER SOURCES, 2012, 219 : 133 - 139
  • [23] Electrochemical performance of unsintered Ba0.5Sr0.5Co0.8Fe0.2O3-δ, La0.6Sr0.4Co0.8Fe0.2O3-δ, and La0.8Sr0.2MnO3-δ cathodes for metal-supported solid oxide fuel cells
    Kim, Yu-Mi
    Kim-Lohsoontorn, Pattaraporn
    Baek, Seung-Wook
    Bae, Joongmyeon
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (04) : 3138 - 3146
  • [24] Interaction of La0.8Sr0.2MnO3 interlayer with Gd0.1Ce0.9O1.95 electrolyte membrane and Ba0.5Sr0.5Co0.8Fe0.2O3-δ cathode in low-temperature solid oxide fuel cells
    Yang, Min
    Zhang, Min
    Yan, Aiyu
    Yue, Mangling
    Hou, Zhifang
    Dong, Yonglai
    Cheng, Mojie
    JOURNAL OF POWER SOURCES, 2008, 185 (02) : 784 - 789
  • [25] Enhanced Chromium Tolerance of Gd0.1Ce0.9O1.95 Impregnated La0.6Sr0.4Co0.2Fe0.8O3-δ Electrode of Solid Oxide Fuel Cells
    Zhao, L.
    Amarasinghe, S.
    Jiang, S. P.
    SOLID OXIDE FUEL CELLS 13 (SOFC-XIII), 2013, 57 (01): : 2163 - 2173
  • [26] A comparison study of chromium deposition and poisoning on La0.8Sr0.2Ga0.8Mg0.2O3-δ and Gd0.1Ce0.9O2-δ electrolytes of solid oxide fuel cells
    Zhao, Ling
    Cui, Yuexiao
    Gui, Liangqi
    Li, Geng
    He, Beibei
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 688 : 376 - 381
  • [27] The effect of phase composition on the transport properties of composites La0.8Sr0.2Fe0.7Ni0.3O3-δ-Ce0.9Gd0.1O1.95
    Okhlupin, Yu. S.
    Ananyev, M. V.
    Uvarov, N. F.
    Bespalko, Yu. N.
    Pavlova, S. N.
    Sadykov, V. A.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2011, 47 (06) : 663 - 670
  • [28] Combined Cr and S poisoning of La0.8Sr0.2MnO3-δ (LSM) cathode of solid oxide fuel cells
    Wang, Cheng Cheng
    Darvish, Shadi
    Chen, Kongfa
    Hou, Bingxue
    Zhang, Qi
    Tan, Zanxiong
    Zhong, Yu
    Jiang, San Ping
    ELECTROCHIMICA ACTA, 2019, 312 (202-212) : 202 - 212
  • [29] Electrochemical Behavior of Nanostructured La0.8Sr0.2MnO3 as Cathodes for Solid Oxide Fuel Cells
    Sacanell, Joaquin
    Sanchez, J. Hernandez
    Rubio Lopez, A. E.
    Martinelli, H.
    Siepe, J.
    Leyva, A. G.
    Ferrari, V. P.
    Pruneda, M.
    Juan, D.
    Lamas, D. G.
    SOLID OXIDE FUEL CELLS 15 (SOFC-XV), 2017, 78 (01): : 667 - 675