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Highly efficient La0.8Sr0.2MnO3-δ - Ce0.9Gd0.1O1.95 nanocomposite cathodes for solid oxide fuel cells
被引:18
|作者:
dos Santos-Gomez, L.
[1
]
Zamudio-Garcia, J.
[1
]
Porras-Vazquez, J. M.
[1
]
Losilla, E. R.
[1
]
Marrero-Lopez, D.
[2
]
机构:
[1] Univ Malaga, Dept Quim Inorgan Cristalog & Mineral, E-29071 Malaga, Spain
[2] Univ Malaga, Dept Fis Aplicada 1, Lab Mat & Superficie, E-29071 Malaga, Spain
关键词:
Solid Oxide Fuel Cells;
La0.8Sr0.2MnO3-delta;
CeO2;
Spray-pyrolysis;
SPRAY-PYROLYSIS;
COMPOSITE CATHODES;
ELECTROCHEMICAL PERFORMANCE;
RATIONAL DESIGN;
TEMPERATURE;
MICROSTRUCTURE;
ELECTRODES;
DEPOSITION;
FILMS;
OPTIMIZATION;
D O I:
10.1016/j.ceramint.2017.12.089
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
La0.8Sr0.2MnO3-delta-Ce0.9Gd0.1O1.95 (LSM-CGO) nanostructured cathodes are successfully prepared in a single process by a chemical spray -pyrolysis deposition method. The cathode is composed of nanometric particles of approximately 15 nm of diameter, providing high triple-phase boundary sites for the oxygen reduction reactions. A low polarization resistance of 0.046 Omega cm(2) is obtained at 700 degrees C, which is comparable to the most efficient cobaltite-based perovskite cathodes. A NiO-YSZ anode supported fuel cell with the nanostructured cathode generates a power output of 1.4 W cm(-2) at 800 degrees C, significantly higher than 0.75 W cm(-2) for a cell with conventional LSM-CGO cathode. The results suggest that this is a promising strategy to achieve high efficiency electrodes for Solid Oxide Fuel Cells in a single preparation step, simplifying notably the fabrication process compared to traditional methods.
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页码:4961 / 4966
页数:6
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