Intramolecular cyclization of alicyclic 1,5-di- and 1,3,5-triketones

被引：6
|
作者：
Akimova, TI [1 ]
Ivanenko, ZA [1 ]
Vysotskii, VI [1 ]
机构：
[1] Far Eastern State Univ, Vladivostok 690600, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 37卷 / 08期
关键词：
D O I：
10.1023/A:1013115625249
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
On a series of 44 alicyclic 1,5-di- and 1,3,5-triketones was studied the influence of various structural factors (size of the 5-7-membered ring, positions of the substituents) on the capability for intramolecular aldol condensation and on its direction. The most prone to this reaction are compounds possessing a 6-membered cycle and a substituent in the beta -methylene bridge. The substituent in alpha -position to one of the carbonyl groups can affect the reaction in two ways depending on the degree of shielding of this position.
引用
收藏
页码：1068 / 1073
页数：6
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