Determination of the amount of reacted metakaolin in calcined clay blends

被引:163
作者
Avet, Francois [1 ]
Li, Xuerun [1 ]
Scrivener, Karen [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Lab Construct Mat, IMX, CH-1015 Lausanne, Switzerland
关键词
Calcined clay; Metakaolin; Mass balance; Thermodynamic modelling; PONKCS; REACTIVITY; MINERALS;
D O I
10.1016/j.cemconres.2018.01.009
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
This paper presents a comparative study of three methods to determine the amount of reacted metakaolin in calcined clay blends: mass balance, thermodynamic modelling, and the Partial or not Known Crystalline Structure method (PONKCS) based on Rietveld analysis of X-ray diffraction. The methods are applied to Limestone calcined clay cements (LC3-50) in this study. Mass balance and thermodynamic modelling results show good agreement, especially at early age. PONKCS method shows globally comparable results, even if it has higher variability. The precision of PONKCS becomes poor for blends with < 60% of metakaolin in calcined clay.
引用
收藏
页码:40 / 48
页数:9
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