Highly symmetric 3D ferrimagnets, [Mn(dien)]3[M(CN)6]2•2H2O (M = Cr, Mn; dien = diethylenetriamine): Synthesis, structures and magnetic properties

被引：2
|
作者：
Kaneko, Wakako [1 ]
Mishima, Akio [2 ]
Ohba, Hisayoshi [2 ]
Kitagawa, Susumu [1 ,3 ]
Ohba, Masaaki [2 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kyushu Univ, Fac Sci, Dept Chem, Fukuoka 8128581, Japan
[3] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan
来源：
POLYHEDRON | 2013年 / 64卷
关键词：
Coordination polymer; Ferrimagnet; Cyanide-bridge; CRYSTAL; FERROMAGNETISM; TRANSITION; BEHAVIOR; TRIAMINE;
D O I：
10.1016/j.poly.2013.03.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cyanide-bridged (MnMIII)-M-II coordination polymers, [Mn(dien)](3)[M(CN)(6)](2)center dot 2H(2)O (M = Cr (1), Mn (2); dien = diethylenetriamine), have been prepared by using [M(CN)(6)](3-) building units and a tridentate dien as a coligand. Single crystal and powder X-ray diffraction results of 1 and 2 proposed that the compounds are isomorphous and form a highly symmetric 3D network based on M8Mn12 cubes consist of [Mn(dien)](2+) cations and mu(6)-, mu(4)-, and unbridged [M(CN)(6)](3-) anions. Both compounds exhibited a ferrimagnetic ordering at 63.4 K (1) and 24.8 K (2) with coercive field of similar to 0 G (1) and 1 kG (2). Their magnetic properties were compared with other cyanide-bridged (MnMIII)-M-II ferrimagnets and the differences were discussed based on the structure and the electric configuration. (C) 2013 Elsevier Ltd. All rights reserved.
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页码：122 / 127
页数：6
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