Fabrication and characterization of low temperature co-fired cordierite glass-ceramics from potassium feldspar

被引:30
作者
Wu, Jianfang [1 ]
Li, Zhen [1 ]
Huang, Yanqiu [1 ]
Li, Fei [1 ]
Yang, Qiuran [1 ]
机构
[1] China Univ Geosci, Fac Mat Sci & Chem, Minist Educ, Engn Res Ctr Nanogeomat, Wuhan 430074, Peoples R China
关键词
Cordierite; Glass-ceramics; Potassium feldspar; LTCC; MICROWAVE DIELECTRIC-PROPERTIES; MULTILAYER CHIP INDUCTORS; ANORTHITE-BASED GLASS; CRYSTALLIZATION; LTCC; COMPOSITES; KAOLIN; TALC;
D O I
10.1016/j.jallcom.2013.08.187
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cordierite glass-ceramics for low temperature co-fired ceramic (LTCC) substrates were fabricated successfully using potassium feldspar as the main raw material. The sintering and crystallization behaviors of the glass-ceramics were investigated by the differential scanning calorimetry (DSC), X-ray diffraction (XRD), and field emission scanning electron microscope (FESEM). The results indicated that the glass-ceramics could be highly densified at 850 degrees C and the cordierite was the main crystalline phase precipitated from the glasses in the temperature range between 900 and 925 degrees C. The study also evaluated the physical properties including dielectric properties, thermal expansion and flexural strength of the glass-ceramics. The glass-ceramics showed low dielectric constants in the range of 6-8 and low dielectric losses in the range of 0.0025-0.01. The coefficients of thermal expansion (CTEs) are between 4.32 and 5.48 x 10(-6) K-1 and flexural strength of the glass-ceramics are 90-130 MPa. All of those qualify the glass-ceramics for further research to be used as potential LTCC substrates in the multilayer electronic substrate field. Additionally, the excess SiO2 acted as a great role in improving the sinterability of the glasses, and the microstructure and dielectric properties of the relevant glass-ceramics. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:248 / 253
页数:6
相关论文
共 36 条
[1]   Crystallisation of non-stoichiometric cordierite glasses [J].
Azín, NJ ;
Camerucci, MA ;
Cavalieri, AL .
CERAMICS INTERNATIONAL, 2005, 31 (01) :189-195
[2]   Effect of impurities content from minerals on phase transformation, densification and crystallization of α-cordierite glass-ceramic [J].
Banjuraizah, Johar ;
Mohamad, Hasmaliza ;
Ahmad, Zainal Arifin .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (28) :7645-7651
[3]   Densification and Crystallization of Nonstoichiometric Cordierite Glass with Excess MgO Synthesized from Kaolin and Talc [J].
Banjuraizah, Johar ;
Mohamad, Hasmaliza ;
Ahmad, Zainal Arifin .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (03) :687-694
[4]   Crystal structure of single phase and low sintering temperature of α-cordierite synthesized from talc and kaolin [J].
Banjuraizah, Johar ;
Mohamad, Hasmaliza ;
Ahmad, Zainal Arifin .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 482 (1-2) :429-436
[5]   Crystallization kinetics and mechanism of low-dielectric, low-temperature, cofirable CaO-B2O3-SiO2 glass-ceramics [J].
Chang, CR ;
Jean, JH .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1999, 82 (07) :1725-1732
[6]   Fabrication, characterization and sintering of glass-ceramics for low-temperature co-fired ceramic substrates [J].
Chen, GH ;
Liu, XY .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2004, 15 (09) :595-600
[7]   Sintering, crystallization, and properties of CaO doped cordierite-based glass-ceramics [J].
Chen, Guo-hua .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 455 (1-2) :298-302
[8]   Effect of ZnO addition on properties of cordierite-based glass-ceramics [J].
Chen, Guo-hua .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2007, 18 (12) :1253-1257
[9]   Sintering, crystallization and properties of MgO-Al2O3-SiO2 system glass-ceramics containing ZnO [J].
Chen, Guo-Hua ;
Liu, Xin-Yu .
JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 431 (1-2) :282-286
[10]   Effects of CaSiO3 addition on sintering behavior and microwave dielectric properties of Al2O3 ceramics [J].
Chen, Jin-min ;
Wang, Huan-ping ;
Feng, Si-qiao ;
Ma, Hong-ping ;
Deng, De-gang ;
Xu, Shi-qing .
CERAMICS INTERNATIONAL, 2011, 37 (03) :989-993