Bringing together fundamental and applied science: The supercritical fluids route

被引:37
作者
Besnard, M
Tassaing, T
Danten, Y
Andanson, JM
Soetens, JC
Cansell, F
Loppinet-Serani, A
Reveron, H
Aymonier, C
机构
[1] Univ Bordeaux 1, CNRS, UMR 5803, Lab Physicochim Mol, F-33405 Talence, France
[2] Univ Bordeaux 1, CNRS, ICMCB, F-33608 Pessac, France
关键词
supercritical fluid; nanomaterial; porous material; polymer; vibrational spectroscopy; ab initio; molecular dynamics;
D O I
10.1016/j.molliq.2005.05.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The aim of this paper is to introduce SCF studies as a domain in which fundamental and applied researches can strongly overlap, thereby offering an original approach to stimulate interdisciplinary cross-studies. After a general presentation of supercritical fluids, some specific properties will be illustrated at the molecular level from the study of typical neat SCF and binary mixtures using vibrational spectroscopy and modelling. This part will be followed by a presentation of current researches at a macroscopic level on materials elaborated in supercritical media namely fine particle and porous materials synthesis and surface modifications. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:88 / 99
页数:12
相关论文
共 43 条
[1]   Hydrogen bonding in supercritical tert-butanol assessed by vibrational spectroscopies and molecular-dynamics simulations -: art. no. 174512 [J].
Andanson, JM ;
Soetens, JC ;
Tassaing, T ;
Besnard, M .
JOURNAL OF CHEMICAL PHYSICS, 2005, 122 (17)
[2]   Supercritical fluid technology of nanoparticle coating for new ceramic materials [J].
Aymonier, C ;
Elissalde, C ;
Reveron, H ;
Weill, F ;
Maglione, M ;
Cansell, F .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2005, 5 (06) :980-983
[3]   HARD FLUID MODEL FOR SOLVENT-INDUCED SHIFTS IN MOLECULAR VIBRATIONAL FREQUENCIES [J].
BENAMOTZ, D ;
HERSCHBACH, DR .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (10) :2295-2306
[4]   Addition of nanosized Cr2O3 to magnesium for improvement of the hydrogen sorption properties [J].
Bobet, JL ;
Desmoulins-Krawiec, S ;
Grigorova, E ;
Cansell, F ;
Chevalier, B .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 351 (1-2) :217-221
[5]   Supercritical fluid processing: a new route for materials synthesis [J].
Cansell, F ;
Chevalier, B ;
Demourgues, A ;
Etourneau, J ;
Even, C ;
Garrabos, Y ;
Pessey, V ;
Petit, S ;
Tressaud, A ;
Weill, F .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (01) :67-75
[6]   Binary mixtures of supercritical carbon dioxide with methanol. A molecular dynamics simulation study [J].
Chatzis, G ;
Samios, J .
CHEMICAL PHYSICS LETTERS, 2003, 374 (1-2) :187-193
[7]   Vibrational spectra of CO2-electron donor -: Acceptor complexes from ab initio [J].
Danten, Y ;
Tassaing, T ;
Besnard, M .
JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (48) :11831-11840
[8]   Synthesis of nanostructured materials in supercritical ammonia: nitrides, metals and oxides [J].
Desmoulins-Krawiec, S ;
Aymonier, C ;
Loppinet-Serani, A ;
Weill, F ;
Gorsse, S ;
Etourneau, J ;
Cansell, F .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (02) :228-232
[9]   TORSIONAL VIBRATIONS AND BARRIERS TO INTERNAL-ROTATION FOR ETHANOL AND 2,2,2-TRIFLUOROETHANOL [J].
DURIG, JR ;
LARSEN, RA .
JOURNAL OF MOLECULAR STRUCTURE, 1990, 238 :195-222
[10]   Local density enhancement in dilute supercritical solutions [J].
Egorov, SA ;
Yethiraj, A ;
Skinner, JL .
CHEMICAL PHYSICS LETTERS, 2000, 317 (06) :558-566