Gold catalysis: First applications of cationic binuclear gold(I) complexes and the first intermolecular reaction of an alkyne with a furan

被引：159

作者：

Hashmi, ASK

Blanco, MC

Kurpejovic, E

Frey, W

Bats, JW

机构：

[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany

[2] Goethe Univ Frankfurt, Inst Organ Chem & Chem Biol, D-60439 Frankfurt, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2006年 / 348卷 / 06期

关键词：

alkynes; arenes; furans; gold; homogeneous catalysis;

D O I：

10.1002/adsc.200606012

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Reaction of the cationic binuclear gold(1) complex [(Ph3PAu)(2)Cl]BF4 with w-alkynylfurans furnished phenols as the major product and anellated furans as the side-products. The analogous trimesityl-phosphane complex [(Mes(3)PAu)(2)Cl]BF4 selectively afforded only the phenols. The latter catalyst then enabled the first intermolecular gold-catalyzed phenol synthesis.

引用

页码：709 / 713

页数：5

共 49 条

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[Anonymous], 2005, ANGEW CHEM, V117, P7150, DOI DOI 10.1002/ANGE.200502735

[2]

[Anonymous], ANGEW CHEM

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