A simple general ligand system for assembling octahedral metal-rotaxane complexes

被引：109

作者：

Hogg, L ^{[1
]}

Leigh, DA ^{[1
]}

Lusby, PJ ^{[1
]}

Morelli, A ^{[1
]}

Parsons, S ^{[1
]}

Wong, JKY ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 10期

关键词：

coordination modes; rotaxanes; self-assembly; template synthesis; thermodynamic control;

D O I：

10.1002/anie.200353186

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Full Metal Jacket: Simple stirring of a five component mixture at room temperature is sufficient to assemble a wide range of octahedrally coordinated [2] metallorotaxanes under thermodynamic control (see picture).

引用

页码：1218 / 1221

页数：4

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