A simple general ligand system for assembling octahedral metal-rotaxane complexes

被引：109
|
作者：
Hogg, L [1 ]
Leigh, DA [1 ]
Lusby, PJ [1 ]
Morelli, A [1 ]
Parsons, S [1 ]
Wong, JKY [1 ]
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 10期
关键词：
coordination modes; rotaxanes; self-assembly; template synthesis; thermodynamic control;
D O I：
10.1002/anie.200353186
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Full Metal Jacket: Simple stirring of a five component mixture at room temperature is sufficient to assemble a wide range of octahedrally coordinated [2] metallorotaxanes under thermodynamic control (see picture).
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页码：1218 / 1221
页数：4
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