A simple general ligand system for assembling octahedral metal-rotaxane complexes

被引：109

作者：

Hogg, L ^{[1
]}

Leigh, DA ^{[1
]}

Lusby, PJ ^{[1
]}

Morelli, A ^{[1
]}

Parsons, S ^{[1
]}

Wong, JKY ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 10期

关键词：

coordination modes; rotaxanes; self-assembly; template synthesis; thermodynamic control;

D O I：

10.1002/anie.200353186

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Full Metal Jacket: Simple stirring of a five component mixture at room temperature is sufficient to assemble a wide range of octahedrally coordinated [2] metallorotaxanes under thermodynamic control (see picture).

引用

页码：1218 / 1221

页数：4

共 50 条

[21] General synthesis of 'salicylaldehyde half-unit complexes': Structural determination and use as synthon for the synthesis of dimetallic or trimetallic complexes and of 'self-assembling ligand complexes'
Lab. de Chim. de Coord. du CNRS, UPR 8241, L'Inst. Natl. Polytech. de Toulouse, 205 route de Narbonne, 31077 Toulouse Cedex, France
不详
Inorg. Chim. Acta, 1 (73-81):
[22] General synthesis of 'salicylaldehyde half-unit complexes': structural determination and use as synthon for the synthesis of dimetallic or trimetallic complexes and of 'self-assembling ligand complexes'
Costes, JP
Dahan, F
Fernandez, MBF
Garcia, MIF
Deibe, AMG
Sanmartin, J
INORGANICA CHIMICA ACTA, 1998, 274 (01) : 73 - 81
[23] Stable transition metal-enol complexes in the cycloheptatriene ligand system
Rigby, JH
Niyaz, NM
Sugathapala, P
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (34) : 8178 - 8179
[24] Heavy metal ion complexes with a simple phenolic ligand. Solid state and solution studies
Ambrosi, G
Formica, M
Fusi, V
Giorgi, L
Guerri, A
Micheloni, M
Paoli, P
Pontellini, R
Rossi, P
INORGANICA CHIMICA ACTA, 2003, 356 : 203 - 209
[25] An octahedral template based on a new molecular turn: Synthesis and structure of a model complex and a reactive, diphenolic ligand and its metal complexes
Vance, AL
Alcock, NW
Heppert, JA
Busch, DH
INORGANIC CHEMISTRY, 1998, 37 (26) : 6912 - 6920
[26] Metal-Ion-Induced Mechanical Chirality: Achiral Rotaxane as the Only Ligand in Chiral Palladium(II)-N-Heterocyclic Carbene Complexes
Cho, Hsien-Liang
Lai, Chien-Chen
Liu, Yi-Hung
Hsu, Hsiu-Fu
Peng, Shie-Ming
Chiu, Sheng-Hsien
ORGANIC LETTERS, 2022, 24 (10) : 1996 - 2001
[27] TROPOCORONANDS - A VERSATILE MACROCYCLIC LIGAND SYSTEM FOR MONONUCLEAR AND BINUCLEAR METAL-COMPLEXES
VILLACORTA, GM
LIPPARD, SJ
PURE AND APPLIED CHEMISTRY, 1986, 58 (11) : 1477 - 1484
[28] Synthesis of a flexible ligand for assembling two metal ions in close proximity. Crystal structures of binuclear nickel and copper complexes
Dapporto, P
Formica, M
Fusi, V
Micheloni, M
Paoli, P
Pontellini, R
Rossi, P
INORGANIC CHEMISTRY, 2000, 39 (20) : 4663 - 4665
[29] SYNTHESIS AND REACTIONS OF PORPHINOID METAL-COMPLEXES .7. PALLADIUM COMPLEXES WITH PORPHINOID LIGAND SYSTEM
GEISSER, P
SCHMID, P
SCHEFFOLD, R
CHIMIA, 1980, 34 (06) : 279 - 280
[30] NEW CHELATE RING-OPENING REACTIONS LEADING TO THE SYNTHESIS OF NOVEL MIXED-LIGAND COMPLEXES OF THE OCTAHEDRAL METAL-CARBONYLS
KING, RB
LEE, TW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 190 (01) : C17 - C20

← 1 2 3 4 5 →