Hydroxylammonium Tetrafluoridooxidovanadate(V) - (NH3OH)[VOF4]

被引：4
|
作者：
Lozinsek, Matic [1 ]
机构：
[1] Jozef Stefan Inst, Dept Inorgan Chem & Technol, Ljubljana 1000, Slovenia
来源：
ACTA CHIMICA SLOVENICA | 2015年 / 62卷 / 02期
关键词：
Fluoridooxidovanadate; Vanadium oxyfluoride; Hydroxylamine; Hydroxylammonium; X-ray crystallography; Anhydrous hydrogen fluoride; BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE; PATTERNS; SPECTRA;
D O I：
10.17344/acsi.2015.1424
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydroxylammonium tetrafluoridooxidovanadate(V) has been prepared by reaction of (NH3OH)Cl and VOF3 in anhydrous HT solvent and characterised in the solid state by single-crystal X-ray diffraction and Raman spectroscopy. Colourless (NH3OH)[VOF4] crystallises in the monoclinic space group P2(1)/n with a = 7.2349(2) angstrom, b = 5.0351(2) angstrom, c = 12.8322(4) angstrom, beta = 94.843(3)degrees, V = 465.79(3) angstrom(3) and Z = 4 at 150 K. The crystal structure of the title compound is comprised of polymeric chain anions, [VOF4](n)(n-), interconnected by hydrogen bonds with hydroxylammonium cations, (NH3OH)(+).
引用
收藏
页码：378 / 384
页数：7
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