1,3-DI(4-PYRIDYL)TRIAZENE: A NEW LIGAND FOR THE SYNTHESIS OF COORDINATION POLYMERS

被引：2

作者：

Romanenko, G. V. ^{[1
]}

Tolstikov, S. E. ^{[1
]}

Fursova, E. Yu ^{[1
]}

Ovcharenko, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Int Tomog Ctr, Siberian Branch, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 61卷 / 05期

基金：

俄罗斯科学基金会;

关键词：

4,4 '-(triaz-1-ene-1,3-diyl)dipyridine; coordination polymer; hexafluoroacetylacetonate; copper; TRIAZENES;

D O I：

10.1134/S0022476620050054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

4,4 '-(Triaz-1-ene-1,3-diyl)dipyridine (L) and the first transition metal complex with it are synthesized. It is found that the solid phase of isolated solvate [Cu(hfac)(2)L].0.5MePh, where hfac is hexafluoroacetylacetonate, consists of polymer chains inside which L acts as a bridge, linking together Cu(hfac)(2)moieties by N atoms of pyridine rings. The chains, in turn, are arranged into layers by H bonds. The result shows that L can be a bridging ligand in the synthesis of new coordination polymers.

引用

页码：707 / 711

页数：5

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