Membrane-less hydrogen bromine flow battery

被引:180
作者
Braff, William A. [1 ]
Bazant, Martin Z. [2 ]
Buie, Cullen R. [1 ]
机构
[1] MIT, Dept Mech Engn, Cambridge, MA 02139 USA
[2] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
关键词
MICROFLUIDIC FUEL-CELL; ENERGY-STORAGE APPLICATIONS; VANADIUM REDOX BATTERY; LAMINAR-FLOW; HIGH-POWER; PERFORMANCE; ELECTRODE; ACID; MICROCHANNELS; TRANSPORT;
D O I
10.1038/ncomms3346
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In order for the widely discussed benefits of flow batteries for electrochemical energy storage to be applied at large scale, the cost of the electrochemical stack must come down substantially. One promising avenue for reducing stack cost is to increase the system power density while maintaining efficiency, enabling smaller stacks. Here we report on a membrane-less hydrogen bromine laminar flow battery as a potential high-power density solution. The membrane-less design enables power densities of 0.795 W cm(-2) at room temperature and atmospheric pressure, with a round-trip voltage efficiency of 92% at 25% of peak power. Theoretical solutions are also presented to guide the design of future laminar flow batteries. The high-power density achieved by the hydrogen bromine laminar flow battery, along with the potential for rechargeable operation, will translate into smaller, inexpensive systems that could revolutionize the fields of large-scale energy storage and portable power systems.
引用
收藏
页数:6
相关论文
共 44 条
[1]   Improved fuel utilization in microfluidic fuel cells: A computational study [J].
Bazylak, A ;
Sinton, D ;
Djilali, N .
JOURNAL OF POWER SOURCES, 2005, 143 (1-2) :57-66
[2]   Hydrogen Bromine Laminar Flow Electrochemical Cell for High Power and Efficiency Energy Storage Applications [J].
Braff, W. A. ;
Buie, C. R. .
BATTERY/ENERGY TECHNOLOGY (GENERAL) - 218TH ECS MEETING, 2011, 33 (39) :179-190
[3]   Numerical and Analytical Modeling of a Membraneless Hydrogen Bromine Laminar Flow Battery [J].
Braff, William A. ;
Buie, Cullen R. ;
Bazant, Martin Z. .
STATIONARY AND LARGE SCALE ELECTRICAL ENERGY STORAGE 2, 2013, 53 (07) :51-62
[4]   Analysis of Pt/C electrode performance in a flowing-electrolyte alkaline fuel cell [J].
Brushett, Fikile R. ;
Naughton, Matthew S. ;
Ng, Jia Wei Desmond ;
Yin, Leilei ;
Kenis, Paul J. A. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (03) :2559-2570
[5]   Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform [J].
Brushett, Fikile R. ;
Zhou, Wei-Ping ;
Jayashree, Ranga S. ;
Kenis, Paul J. A. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (05) :B565-B571
[6]   High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage [J].
Cho, Kyu Taek ;
Ridgway, Paul ;
Weber, Adam Z. ;
Haussener, Sophia ;
Battaglia, Vincent ;
Srinivasan, Venkat .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (11) :A1806-A1815
[7]   Microfluidic fuel cell based on laminar flow [J].
Choban, ER ;
Markoski, LJ ;
Wieckowski, A ;
Kenis, PJA .
JOURNAL OF POWER SOURCES, 2004, 128 (01) :54-60
[8]   A Comparative Ab Initio Study of the Primary Hydration and Proton Dissociation of Various Imide and Sulfonic Acid Ionomers [J].
Clark, Jeffrey K., II ;
Paddison, Stephen J. ;
Eikerling, Michael ;
Dupuis, Michel ;
Zawodzinski, Thomas A., Jr. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 116 (07) :1801-1813
[9]   Fabrication and preliminary testing of a planar membraneless microchannel fuel cell [J].
Cohen, JL ;
Westly, DA ;
Pechenik, A ;
Abruña, HD .
JOURNAL OF POWER SOURCES, 2005, 139 (1-2) :96-105
[10]   KINETICS OF BROMINE/BROMIDE ELECTRODE ON PLATINUM IN AQUEOUS SULPHURIC ACID [J].
COOPER, WD ;
PARSONS, R .
TRANSACTIONS OF THE FARADAY SOCIETY, 1970, 66 (571) :1698-&