Colorimetric and fluorescent sensor for selective sensing of Hg2+ ions in semi aqueous medium

被引：26
|
作者：
Udhayakumari, Duraisamy [1 ]
Velmathi, Sivan [1 ]
机构：
[1] Natl Inst Technol, Organ & Polymer Synth Lab, Dept Chem, Tiruchirappalli 620015, Tamil Nadu, India
来源：
JOURNAL OF LUMINESCENCE | 2013年 / 136卷
关键词：
Colorimetric titration; Hg2+ ion sensor; DMSO: water mixture; UV-vis spectroscopy; Fluorescence spectroscopy; HG2+-SELECTIVE CHEMODOSIMETER; MERCURY LEVELS; METAL-IONS; WATER; CHEMOSENSORS; SPIROLACTAM; MOLECULES; RECEPTOR; BINDING; HG(II);
D O I：
10.1016/j.jlumin.2012.11.011
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
A highly sensitive and selective detection of Hg2+ ion with simple salophen probe was developed. In DMSO: water (40:60, v/v) solution, Hg2+ ions coordinate with imine and shows color turn-off from yellow to colorless. Receptor 1 showed its ability for sensing Hg2+ cations sensitively through three channels: colorimetric, UV-vis and fluorescence spectroscopy. Hg2+ ions coordinate to the imine (Receptor 1) through NONO binding site forming 1:1 complex. It exhibits fluorescent 'Turn-on' behavior based on solvent polarity. The detection limit of our receptor with mercury is 1 mu g L-1. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：117 / 121
页数：5
相关论文
共 50 条
  • [31] A highly selective colorimetric sensor for Hg2+ based on a copper (Ⅱ) complex of thiosemicarbazone in aqueous solutions
    WEI TaiBao
    LI JunJian
    BAI CuiBing
    LIN Qi
    YAO Hong
    XIE YongQiang
    ZHANG YouMing
    Science China(Chemistry), 2013, 56 (07) : 923 - 927
  • [32] A rhodamine-based fluorescent and colorimetric chemodosimeter for the rapid detection of Hg2+ ions in aqueous media
    Yang, YK
    Yook, KJ
    Tae, J
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (48) : 16760 - 16761
  • [33] A NBD-based selective colorimetric and fluorescent chemosensor for Hg2+
    Kim, Jin Hoon
    Noh, Jin Young
    Hwang, In Hong
    Lee, Jae Jun
    Kim, Cheal
    TETRAHEDRON LETTERS, 2013, 54 (30) : 4001 - 4005
  • [34] Functionalized mesoporous silica as a fluorescence sensor for selective detection of Hg2+ in aqueous medium
    Huang, Jing
    Liu, Hai-Bo
    Wang, Jing
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2021, 246
  • [35] A rhodamine-based colorimetric and fluorescent probe for dual sensing of Cu2+ and Hg2+ ions
    Ozdemir, Mecit
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2016, 318 : 7 - 13
  • [36] Single sensor for two metal ions: Colorimetric recognition of Cu2+ and fluorescent recognition of Hg2+
    Tang, Lijun
    Li, Fangfang
    Liv, Minghui
    Nandhakumar, Raju
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 78 (03) : 1168 - 1172
  • [37] Highly effective fluorescent sensor for Hg2+ in aqueous solution
    Kwon, JY
    Soh, JH
    Yoon, YJ
    Yoon, J
    SUPRAMOLECULAR CHEMISTRY, 2004, 16 (08) : 621 - 624
  • [38] A selective, fluorescent probe for Hg2+ detection in aqueous solution
    Zeng, De X.
    Chen, Yi
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 186 (2-3) : 121 - 124
  • [39] A highly selective fluorescent chemosensor for Hg2+ in aqueous solution
    Wang, L
    Wong, WK
    Wu, L
    Li, ZY
    CHEMISTRY LETTERS, 2005, 34 (07) : 934 - 935
  • [40] Biosynthesized unmodified silver nanoparticles: A colorimetric optical sensor for detection of Hg2+ ions in aqueous solution
    Sanjeevappa, Harisha K.
    Nilogal, Parushuram
    Rayaraddy, Ranjana
    Martis, Lavita J.
    Osman, Samir M.
    Badiadka, Narayana
    Yallappa, Sangappa
    RESULTS IN CHEMISTRY, 2022, 4
12345