MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

被引：237
作者：
Canivet, Jerome [1 ]
Aguado, Sonia [1 ]
Schuurman, Yves [1 ]
Farrusseng, David [1 ]
机构：
[1] Univ Lyon 1, CNRS, Inst Rech Catalyse & Environm Lyon IRCELYON, F-69626 Villeurbanne, France
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 11期
基金：
欧盟第七框架计划;
关键词：
METAL-ORGANIC FRAMEWORKS; SURFACE ORGANOMETALLIC CHEMISTRY; NICKEL-COMPLEXES BEARING; HIGHER OLEFINS PROCESS; HETEROGENEOUS CATALYSIS; METALLOCENE CATALYSTS; DIIMINE CATALYSTS; OLIGOMERIZATION; POLYMERIZATION; SILICA;
D O I：
10.1021/ja312120x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.
引用
收藏
页码：4195 / 4198
页数：4
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