Process optimization of adsorption of Cr(VI) on adsorbent prepared from Bauhinia rufescens pod by Box-Behnken Design

被引:14
作者
Alabi, Olushola [1 ]
Olanrewaju, Alade Abass [2 ]
Afolabi, Tinuade Jolaade [1 ]
机构
[1] Ladoke Akintola Univ Technol, Fac Engn & Technol, Ogbomosho, Nigeria
[2] Ladoke Akintola Univ Technol, Fac Engn & Technol Chem Engn, Ogbomosho, Nigeria
关键词
Adsorption; adsorbent; Bauhinia rufescens; Box-Behnken Design; chromium; optimization; ACTIVATED CARBON; WASTE-WATER; AQUEOUS-SOLUTIONS; CATALYZED ESTERIFICATION; HEXAVALENT CHROMIUM; HEAVY-METAL; REMOVAL; IONS; BIOSORPTION; KINETICS;
D O I
10.1080/01496395.2019.1577436
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This study investigated chromium (VI) removal from simulated water using H3PO4 modified Bauhinia rufescens pod (ACBRP). Box-Behnken Design was used to optimize pH (2-10), time (30-120 min), agitation (120-200 rpm), and temperature (25-40 degrees C) for the adsorption process. Highest adsorption capacity (AC) and removal efficiency (RE) obtained were 9.762 mg/g and 87.62%. Correlation coefficient of the quadratic models developed was 0.9822 and 0.9790 for AC and RE, respectively. Second-order kinetic model fitted well the data while Weber Morris model is the preferred film diffusion mechanism. ACBRP was found to be effective for chromium (VI) removal.
引用
收藏
页码:47 / 60
页数:14
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