Application of 1H DOSY for Facile Measurement of Polymer Molecular Weights

被引：190

作者：

Li, Weibin ^{[2
]}

Chung, Hoyong ^{[2
]}

Daeffler, Chris ^{[2
]}

Johnson, Jeremiah A. ^{[1
]}

Grubbs, Robert H. ^{[2
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

[2] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

MACROMOLECULES | 2012年 / 45卷 / 24期

关键词：

LIVING RADICAL POLYMERIZATION; DIFFUSION NMR-SPECTROSCOPY; CHIRAL LITHIUM AMIDE; METATHESIS POLYMERIZATION; RAFT PROCESS; CHEMISTRY; DISTRIBUTIONS; AGGREGATION; SIZE; OLD;

D O I：

10.1021/ma301666x

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

To address the practical issues of polymer molecular weight determination, the first accurate polymer weight-average molecular weight determination method in diverse living/controlled polymerization via DOSY (diffusion-ordered NMR spectroscopy) is reported. Based on the linear correlation between the logarithm of diffusion coefficient (log D) and the molecular weights (log M-w), external calibration curves were created to give predictions of molecular weights of narrowly dispersed polymers. This method was successfully applied to atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), and ring-opening metathesis polymerization (ROMP), with weight-average molecular weights given by this method closely correlated to those obtained from GPC measurement.

引用

页码：9595 / 9603

页数：9

共 50 条

[1] Polymer Molecular Weights via DOSY NMR
Ruzicka, Eric
Pellechia, Perry
Benicewicz, Brian C.
ANALYTICAL CHEMISTRY, 2023, 95 (20) : 7849 - 7854
[2] New validation of molecular mass measurements by means of 2D DOSY 1H NMR experiments: Application to surfactants
Hologne, Maggy
Gaubert, Alexandra
Sanglar, Corinne
Bordes, Claire
Casabianca, Herve
COMPTES RENDUS CHIMIE, 2015, 18 (02) : 187 - 192
[3] Aggregation studies of organolithium complexes by 6Li DOSY, 1H DOSY and 1H, 6Li HOESY NMR methods
Li, Weibin
Kagan, Gerald L.
Hopson, Russell
Williard, Paul G.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
[4] Characterization of heroin samples by 1H NMR and 2D DOSY 1H NMR
Balayssac, Stephane
Retailleau, Emmanuel
Bertrand, Genevieve
Escot, Marie-Pierre
Martino, Robert
Malet-Martino, Myriam
Gilard, Veronique
FORENSIC SCIENCE INTERNATIONAL, 2014, 234 : 29 - 38
[5] Study of the Influence of Resins on the Asphaltene Aggregates by 1H DOSY NMR
Madeira, Nata C. L.
Rainha, Karla P.
Mendonca, Janur
Lacerda, Valdemar, Jr.
Chinelatto, Luiz S., Jr.
de Menezes, Sonia M. C.
Porto, Christiane F. de C.
Pinto, Fernanda E.
Filgueiras, Paulo R.
Romao, Wanderson
Neto, Alvaro C.
ENERGY & FUELS, 2020, 34 (05) : 5679 - 5688
[6] Suppression of 13C satellites in 1H DOSY spectra
Moutzouri, Pinelopi
Kiraly, Peter
Foroozandeh, Mohammadali
Phillips, Andrew R.
Coombes, Steven R.
Nilsson, Mathias
Morris, Gareth A.
JOURNAL OF MAGNETIC RESONANCE, 2018, 295 : 6 - 11
[7] Polymer Molecular Weight Analysis by 1H NMR Spectroscopy
Izunobi, Josephat U.
Higginbotham, Clement L.
JOURNAL OF CHEMICAL EDUCATION, 2011, 88 (08) : 1098 - 1104
[8] 1H and DOSY NMR spectroscopy analysis of Ligusticum porteri rhizome extracts
Leon, Alejandra
Isabel Chavez, Mara
Delgado, Guillermo
MAGNETIC RESONANCE IN CHEMISTRY, 2011, 49 (08) : 469 - 476
[9] 1H DOSY NMR Determination of the Molecular Weight and the Solution Properties of Poly(N-acryloylmorpholine) in Various Solvents
Chamignon, Cecile
Duret, Damien
Charreyre, Marie-Therese
Favier, Arnaud
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2016, 217 (20) : 2286 - 2293
[10] Diffusion (DOSY) 1H NMR as an Alternative Method for Molecular Weight Determination of Poly(ethylene furanoate) (PEF) Polyesters
Rosenboom, Jan-Georg
De Roo, Jonathan
Storti, Giuseppe
Morbidelli, Massimo
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2017, 218 (01)

← 1 2 3 4 5 →