Synthesis and luminescence property of Li2BaP2O7: Ln3+ (Ln = Eu, Sm) phosphors

被引:49
作者
Wani, J. A. [1 ]
Dhoble, N. S. [2 ]
Kokode, N. S. [3 ]
Raju, B. Deva Prasad [4 ]
Dhoble, S. J. [1 ]
机构
[1] RTM Nagpur Univ, Dept Phys, Nagpur 440033, Maharashtra, India
[2] Sevadal Mahila Mahavidhyalaya, Dept Chem, Nagpur 440009, Maharashtra, India
[3] BCUD Gondwana Univ, Gadchiroli, India
[4] Sri Venkateswara Univ, Dept Future Studies, Tirupati 517502, Andhra Pradesh, India
关键词
Lithium barium diphosphate; Luminescence; Phosphors; Solid state lighting; PHOTOLUMINESCENCE PROPERTIES; INTENSITIES; IONS;
D O I
10.1016/j.jlumin.2013.10.007
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Phosphate compounds as host materials are always a good choice for lanthanides to exhibit luminescence. The novel phosphors of Li2BaP2O7 activated with the trivalent Eu3+ and Sm3+ ions were synthesized by high temperature solid state reaction. In characterization, crystallization, morphology and luminescent properties of lithium barium diphosphate were investigated. The excitation and emission spectra were recorded to study the luminescence properties. The as prepared powders of Eu3+ and Sm3+ ions doped Li2BaP2O7 emit reddish orange light, corresponding to D-5(0)-> F-7(1)(595 nm) and (4)G(5/2)-> H-6(7/2)(599 nm) transitions, respectively. The study is novel as no such luminescence data are available for this compound. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:223 / 228
页数:6
相关论文
共 31 条
[1]  
Carnall W. T., 1978, ENERGY LEVEL STRUCTU
[2]   Novel multiband luminescence of Y2Zr2O7:Eu3+, R3+ (R = Ce, Bi) orange-red phosphors via a sol-gel combustion approach [J].
Du, Qingqing ;
Zhou, Guangjun ;
Zhou, Haifeng ;
Yang, Zhongsen .
OPTICAL MATERIALS, 2012, 35 (02) :257-262
[3]  
Gschneidner K.A., 1998, Handbook on the Physics and Chemistry of Rare Earths, V25
[4]   Nucleation sequence on the cation exchange process between Y0.95Eu0.05PO4 and CePO4 nanorods [J].
Gulnar, Abdul Karim ;
Sudarsan, Vasanthakumaran ;
Vatsa, Rajesh Kumar ;
Sakuntala, Tyagarajan ;
Tyagi, Awesh Kumar ;
Gautam, Ujjal Kumar ;
Vinu, Ajayan .
NANOSCALE, 2010, 2 (12) :2847-2854
[5]   Influence of fuels on the morphology of undoped Y3Al5O12 and photoluminescence of Y3Al5O12:Eu3+ prepared by a combustion method [J].
Guo, Kai ;
Zhang, Xue-Mei ;
Chen, Hao-Hong ;
Yang, Xin-Xin ;
Guo, Xiangxin ;
Zhao, Jing-Tai .
MATERIALS RESEARCH BULLETIN, 2010, 45 (09) :1157-1161
[6]   Phosphor Development and Integration for Near-UV LED Solid State Lighting [J].
Han, J. K. ;
Choi, J. I. ;
Piquette, A. ;
Hannah, M. ;
Anc, M. ;
Galvez, M. ;
Talbot, J. B. ;
McKittrick, J. .
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2013, 2 (02) :R3138-R3147
[7]   Crystal-Field Splitting of the Bright Eu3+ Ions in YPO4 Micro-crystals Detected by Zeeman Splitting in Pulsed High Magnetic Fields [J].
Han, Y. ;
Du, G. ;
Han, J. ;
Kan, X. ;
Li, L. .
JOURNAL OF LOW TEMPERATURE PHYSICS, 2013, 170 (5-6) :430-435
[8]   50th anniversary of the Judd-Ofelt theory: An experimentalist's view of the formalism and its application [J].
Hehlen, Markus P. ;
Brik, Mikhail G. ;
Kraemer, Karl W. .
JOURNAL OF LUMINESCENCE, 2013, 136 :221-239
[9]  
Henderson B., 1989, OPTICAL SPECTROSCOPY
[10]   Relationship between structural characteristics and photoluminescent properties of (La1-xEux)2M2O7 (M = Zr, Hf, Sn) pyrochlores [J].
Hirayama, Masaaki ;
Sonoyama, Noriyuki ;
Yamada, Atsuo ;
Kanno, Ryoji .
JOURNAL OF LUMINESCENCE, 2008, 128 (11) :1819-1825