(±)-12-oxotricyclo[6.2.2.01,6]dodecane-10-carboxylic acid:: hydrogen bonding in a tricyclic δ-keto acid

被引：1

作者：

Papadakis, MM ^{[1
]}

Martins, SP ^{[1
]}

Thompson, HW ^{[1
]}

Lalancette, RA ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem, Carl A Olson Mem Labs, Newark, NJ 07102 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2002年 / 58卷 / 06期

关键词：

D O I：

10.1107/S0108270102006893

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ring system of the title compound, C13H18O3, was synthesized by addition of ethyl acrylate to the dienamine of 2-octalone. The keto acid aggregates in the solid as acid-to-acid dimers [O⋯O = 2.663 (2) Å and O-H⋯O = 170 (3)°] whose centrosymmetric hydrogen bonds lie across the a edges and the center of the chosen cell. Three intermolecular C-H⋯O close contacts within 2.7 Å were found involving the ketone group.

引用

页码：O321 / O322

页数：2

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