Synthesis, characterization and theoretical study of 2-azido-4-nitroimidazole-based energetic salts

被引:7
作者
Hou, Ke-Hui [1 ]
Ma, Cong-Ming [1 ]
Liu, Zu-Liang [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
关键词
Synthesis; Energetic compounds; Heats of formation; 2-Azido-4-nitroimidazole; CRYSTAL-STRUCTURE; LATTICE ENERGIES; DETONATIONS; CHEMISTRY; VOLUMES;
D O I
10.1016/j.cclet.2013.12.007
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 2-azido-4-nitroimidazole-based energetic salts were synthesized in a simple and straightforward manner. The structures of these new salts were determined by IR, H-1 NMR and C-13 NMR spectroscopy and elemental analysis. These salts also exhibited high positive enthalpies of formation, high nitrogen content, and moderate detonation properties. (C) 2013 Zu-Liang Liu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码:438 / 440
页数:3
相关论文
共 18 条
  • [11] Relationships among ionic lattice energies, molecular (formula unit) volumes, and thermochemical radii
    Jenkins, HDB
    Roobottom, HK
    Passmore, J
    Glasser, L
    [J]. INORGANIC CHEMISTRY, 1999, 38 (16) : 3609 - 3620
  • [12] CHEMISTRY OF DETONATIONS .2. BUFFERED EQUILIBRIA
    KAMLET, MJ
    ABLARD, JE
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (01) : 36 - &
  • [13] CHEMISTRY OF DETONATIONS .I. A SIMPLE METHOD FOR CALCULATING DETONATION PROPERTIES OF C-H-N-O EXPLOSIVES
    KAMLET, MJ
    JACOBS, SJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (01) : 23 - &
  • [14] Energetic nitrogen-rich salts and ionic liquids
    Singh, Rajendra P.
    Verma, Rajendar D.
    Meshri, Dayal T.
    Shreeve, Jean'ne M.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (22) : 3584 - 3601
  • [15] Tetraanionic Nitrogen-Rich Tetrazole-Based Energetic Salts
    Srinivas, Dharavath
    Ghule, Vikas D.
    Muralidharan, Krishnamurthi
    Jenkins, H. Donald B.
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (05) : 1023 - 1028
  • [16] Synthesis, Crystal Structure and Thermal Analysis of Two New Energetic Compounds (AIM)NO3 and (AIM)(HTNR)•H2O
    Tang Zhan
    Yang Li
    Qiao Xiaojing
    Zhang Tonglai
    Zhang Jianguo
    Liang Yanhui
    [J]. ACTA CHIMICA SINICA, 2012, 70 (04) : 471 - 478
  • [17] Tang Z, 2012, CHEM RES CHINESE U, V28, P4
  • [18] Nitramines with Varying Sensitivities: Functionalized Dipyrazolyl- N-nitromethanamines as Energetic Materials
    Zhang, Jiaheng
    He, Chunlin
    Parrish, Damon A.
    Shreeve, Jean'ne M.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (27) : 8929 - 8936