Transition-Metal-Catalyzed Asymmetric Hydrogenation and Transfer Hydrogenation: Sustainable Chemistry to Access Bioactive Molecules

被引：58

作者：

Ayad, Tahar ^{[1
]}

Phansavath, Phannarath ^{[1
]}

Ratovelomanana-Vidal, Virginie ^{[1
]}

机构：

[1] PSL Res Univ, Chim ParisTech, Inst Rech Chim Paris, CNRS, 11 Rue Pierre & Marie Curie, F-75005 Paris, France

来源：

CHEMICAL RECORD | 2016年 / 16卷 / 06期

关键词：

asymmetric catalysis; dynamic kinetic resolution; hydrogenation; transfer hydrogenation; total synthesis; DYNAMIC KINETIC RESOLUTION; KETO ESTER HYDROCHLORIDES; EFFICIENT ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; CHIRAL LIGANDS; SELECTIVE HYDROGENATION; RUTHENIUM(II) CATALYST; CONJUGATE ADDITION; CARBONYL-COMPOUNDS; IRIDIUM COMPLEX;

D O I：

10.1002/tcr.201600100

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over the last few decades, the development of new and highly efficient synthetic methods to obtain chiral compounds has become an increasingly important and challenging research area in modern synthetic organic chemistry. In this account, we review recent work from our laboratory toward the synthesis of valuable chiral building blocks through transition-metal-catalyzed asymmetric hydrogenation and transfer hydrogenation of C=O, C=N and C=C bonds. Application to the synthesis of biologically relevant products is also described.

引用

页码：2754 / 2771

页数：18

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