Graphite-to-Graphene: Total Conversion

被引:129
作者
Buzaglo, Matat [1 ]
Bar, Ilan Pri [1 ]
Varenik, Maxim [1 ]
Shunak, Liran [1 ]
Pevzner, Svetlana [2 ]
Regev, Oren [1 ,3 ]
机构
[1] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel
[2] Nucl Res Ctr Negev, Dept Chem, IL-84190 Beer Sheva, Israel
[3] Ben Gurion Univ Negev, Ilse Katz Inst Nanoscale Sci & Technol, IL-84105 Beer Sheva, Israel
关键词
aromatic diluents; ball-milling; graphene; top-down synthesis; FEW-LAYER GRAPHENE; SCALABLE PRODUCTION; EXFOLIATION; ENERGY;
D O I
10.1002/adma.201603528
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rush to develop graphene applications mandates mass production of graphene sheets. However, the currently available complex and expensive production technologies are limiting the graphene commercialization. The addition of a protective diluent to graphite during ball-milling is demonstrated to result in a game-changer yield (>90%) of defect-free graphene, whose size is controlled by the milling energy and the diluent type.
引用
收藏
页数:5
相关论文
共 29 条
[1]   Hallmarks of mechanochemistry: from nanoparticles to technology [J].
Balaz, Peter ;
Achimovicova, Marcela ;
Balaz, Matej ;
Billik, Peter ;
Cherkezova-Zheleva, Zara ;
Manuel Criado, Jose ;
Delogu, Francesco ;
Dutkova, Erika ;
Gaffet, Eric ;
Jose Gotor, Francisco ;
Kumar, Rakesh ;
Mitov, Ivan ;
Rojac, Tadej ;
Senna, Mamoru ;
Streletskii, Andrey ;
Wieczorek-Ciurowa, Krystyna .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (18) :7571-7637
[2]   Adsorption of Aromatic and Anti-Aromatic Systems on Graphene through π-π Stacking [J].
Bjoerk, Jonas ;
Hanke, Felix ;
Palma, Carlos-Andres ;
Samori, Paolo ;
Cecchini, Marco ;
Persson, Mats .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (23) :3407-3412
[3]   MECHANICAL ALLOYING OF THE FE-ZR SYSTEM - CORRELATION BETWEEN INPUT ENERGY AND END-PRODUCTS [J].
BURGIO, N ;
IASONNA, A ;
MAGINI, M ;
MARTELLI, S ;
PADELLA, F .
NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1991, 13 (04) :459-476
[4]   Graphite-to-Graphene: Total Conversion [J].
Buzaglo, Matat ;
Bar, Ilan Pri ;
Varenik, Maxim ;
Shunak, Liran ;
Pevzner, Svetlana ;
Regev, Oren .
ADVANCED MATERIALS, 2017, 29 (08)
[5]   Critical parameters in exfoliating graphite into graphene [J].
Buzaglo, Matat ;
Shtein, Michael ;
Kober, Sivan ;
Lovrincic, Robert ;
Vilan, Ayelet ;
Regev, Oren .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (12) :4428-4435
[6]   Nanoporous carbon produced by ball milling [J].
Chen, Y ;
Fitz Gerald, JD ;
Chadderton, LT ;
Chaffron, L .
APPLIED PHYSICS LETTERS, 1999, 74 (19) :2782-2784
[7]   Probing the Nature of Defects in Graphene by Raman Spectroscopy [J].
Eckmann, Axel ;
Felten, Alexandre ;
Mishchenko, Artem ;
Britnell, Liam ;
Krupke, Ralph ;
Novoselov, Kostya S. ;
Casiraghi, Cinzia .
NANO LETTERS, 2012, 12 (08) :3925-3930
[8]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[9]   The energy efficiency of ball milling in comminution [J].
Fuerstenau, DW ;
Abouzeid, AZM .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2002, 67 (1-4) :161-185
[10]   Ball-milling:: the behavior of graphite as a function of the dispersal media [J].
Janot, R ;
Guérard, D .
CARBON, 2002, 40 (15) :2887-2896