A thermodynamic description of data for pure Pb from 0 K using the expanded Einstein model for the solid and the two state model for the liquid phase

被引：35

作者：

Khvan, A. V. ^{[1
]}

Dinsdale, A. T. ^{[2
,4
]}

Uspenskaya, I. A. ^{[3
]}

Zhilin, M. ^{[1
,3
]}

Babkina, T. ^{[3
]}

Phiri, A. M. ^{[1
]}

机构：

[1] NUST MISIS, Thermochem Mat SRC, Leninskiy Prosp 4, Moscow 199049, Russia

[2] Hampton Thermodynam, Hampton, Middx, England

[3] Lomonosov Moscow State Univ, Lab Chem Thermodynam, 1-3 Leninskiye Gory, Moscow 119991, Russia

[4] Brunel Univ London, BCAST, Uxbridge UB8 3PH, Middx, England

来源：

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2018年 / 60卷

基金：

奥地利科学基金会;

关键词：

Lead; Two state model for liquid phase; Thermodynamic assessment; Extended Einstein model; DIFFERENTIAL SCANNING CALORIMETRY; HEAT-CAPACITY; THERMAL-ANALYSIS; METALS; LEAD; FUSION; TEMPERATURE; ENTHALPY; VALUES; SILVER;

D O I：

10.1016/j.calphad.2017.12.008

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermodynamic data for the crystalline and liquid phases of pure lead were critically assessed. A thermodynamic description was obtained using an extended Einstein model for the crystalline phase and a two state model for the liquid phase. The assessment was carried out through careful analysis of the experimental data published in the scientific literature. Additional measurements using enthalpy drop were also carried out in the present work to remove ambiguities in published experimental data.

引用

页码：144 / 155

页数：12

共 48 条

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