Crystal structure of (η5-pentamethylcyclopentadienyl){bis(pentafluorophenyl)xthiomethylphenyl phosphine-κ 2 S,P)chloro-iridium(III) tetrafluoroborate

被引：0

作者：

Bellabarba, R. M. ^{[1
]}

Nieuwenhuyzen, M. ^{[1
]}

Saunders, G. C. ^{[2
]}

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5BA, Antrim, North Ireland

[2] Univ Waikato, Dept Chem, Hamilton 3240, New Zealand

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 02期

关键词：

conglomerate; eta(5)-pentamethylcyclopentadienyl; iridium; X-ray structure; COMPLEXES; RHODIUM; IRIDIUM; PENTAMETHYLCYCLOPENTADIENYL; LIGANDS;

D O I：

10.1134/S0022476613020315

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The salt (eta(5)-pentamethylcyclopentadienyl){bis(pentafluorophenyl)thiomethylphenylphosphine-kappa(2) S,P)chloroiridium(III) tetrafluoroborate, [(eta(5)-C5Me5)IrCl{kappa(2) S,P-(C6F5)(2)PC6H4SMe-2}]BF4, crystallizes as a conglomerate in the orthorhombic crystal system in space group P2(1)2(1)2(1) with unit cell parameters a = 9.9621(9) , b = 16.7793(15) , c = 18.5040(16) , V = 3093.1(5) (3), Z = 4, d (calc) = 2.014 g center dot cm(-3). The structure of the S (Ir), S (S) stereoisomer reveals three-legged piano stool geometry about Ir, with Cp*-Ir, Ir-P, Ir-S and Ir-Cl distances of 1.847(5) , 2.2791(14) , 2.3451(13) , and 2.3840(12) respectively.

引用

页码：471 / 473

页数：3

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