Catalytic hydrolysis of s-triazine compounds over Al2O3

被引:24
作者
Zhan, ZQ
Mullner, M
Lercher, JA
机构
[1] UNIV TWENTE,FAC CHEM TECHNOL,7500 AE ENSCHEDE,NETHERLANDS
[2] CHEM LINZ GMBH,A-2021 LINZ,AUSTRIA
关键词
hydrolysis; s-triazine; aluminium oxide;
D O I
10.1016/0920-5861(95)00185-9
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Hydrolysis of cyanuric acid, melamine, melem, atrazine and melamine-formaldehyde resin was found to be catalyzed by an Al2O3 catalyst. The reactions occur irreversibly with cleavage of the s-triazine ring between 240 and 450 degrees C. The s-triazine-ring is hydrolyzed to ammonia and carbon dioxide, and the substituted groups to the corresponding molecules by addition of hydrogen.
引用
收藏
页码:167 / 173
页数:7
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