TiO2 nanofiber solid-state dye sensitized solar cells with thin TiO2 hole blocking layer prepared by atomic layer deposition

被引:12
作者
Li, Jinwei [1 ]
Chen, Xi [1 ]
Xu, Weihe [1 ]
Nam, Chang-Yong [2 ]
Shi, Yong [1 ]
机构
[1] Stevens Inst Technol, Dept Mech Engn, Hoboken, NJ 07030 USA
[2] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA
基金
美国国家科学基金会;
关键词
Solid-state dye sensitized solar cells; Titanium dioxide; Nanofibers; Atomic layer deposition; PERFORMANCE; EFFICIENCY; RECOMBINATION; ELECTROLYTE;
D O I
10.1016/j.tsf.2013.03.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We incorporated a thin but structurally dense TiO2 layer prepared by atomic layer deposition (ALD) as an efficient hole blocking layer in the TiO2 nanofiber based solid-state dye sensitized solar cell (ss-DSSC). The nanofiber ss-DSSCs having ALD TiO2 layers displayed increased open circuit voltage, short circuit current density, and power conversion efficiency compared to control devices with blocking layers prepared by spin-coating liquid TiO2 precursor. We attribute the improved photovoltaic device performance to the structural integrity of ALD-coated TiO2 layer and consequently enhanced hole blocking effect that results in reduced dark leakage current and increased charge carrier lifetime. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:275 / 279
页数:5
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