Manufacturing Macroporous Monoliths of Microporous Metal-Organic Frameworks

被引：30

作者：

Widmer, Remo N. ^{[1
]}

Lampronti, Giulio I. ^{[1
]}

Kunz, Benjamin ^{[2
]}

Battaglia, Corsin ^{[2
]}

Shepherd, Jennifer H. ^{[3
]}

Redfern, Simon A. T. ^{[1
]}

Bennett, Thomas D. ^{[3
]}

机构：

[1] Univ Cambridge, Dept Earth Sci, Downing St, Cambridge CB2 3EQ, England

[2] Empa, Swiss Fed Labs Mat Sci & Technol, Ueberlandstr 129, CH-8600 Dubendorf, Switzerland

[3] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England

来源：

ACS APPLIED NANO MATERIALS | 2018年 / 1卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

metal-organic frameworks; zeolitic imidazolate frameworks; porosity; sintering; monoliths; AMORPHIZATION; SEPARATION; ADSORPTION;

D O I：

10.1021/acsanm.7b00335

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We report the first use of a pressure-assisted sintering technique on metal organic framework powders, allowing for the fast production of crystalline macroporous monoliths. Mechanical and microstructural characterization of the monoliths is presented. The interconnected macroporosity of the compacts can be adjusted, providing an immense interface for gas solid interaction. The sintering technique is well-established and commercially available, allowing industrial scale-up of the process.

引用

页码：497 / 500

页数：7

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