Manufacturing Macroporous Monoliths of Microporous Metal-Organic Frameworks

被引：30
|
作者：
Widmer, Remo N. [1 ]
Lampronti, Giulio I. [1 ]
Kunz, Benjamin [2 ]
Battaglia, Corsin [2 ]
Shepherd, Jennifer H. [3 ]
Redfern, Simon A. T. [1 ]
Bennett, Thomas D. [3 ]
机构：
[1] Univ Cambridge, Dept Earth Sci, Downing St, Cambridge CB2 3EQ, England
[2] Empa, Swiss Fed Labs Mat Sci & Technol, Ueberlandstr 129, CH-8600 Dubendorf, Switzerland
[3] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England
来源：
ACS APPLIED NANO MATERIALS | 2018年 / 1卷 / 02期
基金：
英国工程与自然科学研究理事会;
关键词：
metal-organic frameworks; zeolitic imidazolate frameworks; porosity; sintering; monoliths; AMORPHIZATION; SEPARATION; ADSORPTION;
D O I：
10.1021/acsanm.7b00335
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
We report the first use of a pressure-assisted sintering technique on metal organic framework powders, allowing for the fast production of crystalline macroporous monoliths. Mechanical and microstructural characterization of the monoliths is presented. The interconnected macroporosity of the compacts can be adjusted, providing an immense interface for gas solid interaction. The sintering technique is well-established and commercially available, allowing industrial scale-up of the process.
引用
收藏
页码：497 / 500
页数：7
相关论文
共 50 条
  • [1] Microporous Metal-Organic Frameworks for Gas Separation
    Li, Bin
    Wang, Hailong
    Chen, Banglin
    CHEMISTRY-AN ASIAN JOURNAL, 2014, 9 (06) : 1474 - 1498
  • [2] Ligand Functionalization and Its Effect on CO2 Adsorption in Microporous Metal-Organic Frameworks
    Liu, Hui
    Zhao, Yonggang
    Zhang, Zhijuan
    Nijem, Nour
    Chabal, Yves J.
    Peng, Xiangfang
    Zeng, Heping
    Li, Jing
    CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (04) : 778 - 785
  • [3] Microporous metal-organic frameworks for acetylene storage and separation
    Zhang, Zhangjing
    Xiang, Shengchang
    Chen, Banglin
    CRYSTENGCOMM, 2011, 13 (20): : 5983 - 5992
  • [4] Microporous metal-organic frameworks: Synthesis and applications
    Ahmadi, Mahnaz
    Ebrahimnia, Maryam
    Shahbazi, Mohammad-Ali
    Kecili, Rustem
    Ghorbani-Bidkorbeh, Fatemeh
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2022, 115 : 1 - 11
  • [5] Metal-Organic Frameworks: Opportunities for Catalysis
    Farrusseng, David
    Aguado, Sonia
    Pinel, Catherine
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) : 7502 - 7513
  • [6] Metal-Ion Metathesis in Metal-Organic Frameworks: A Synthetic Route to New Metal-Organic Frameworks
    Kim, Yonghwi
    Das, Sunirban
    Bhattacharya, Saurav
    Hong, Soonsang
    Kim, Min Gyu
    Yoon, Minyoung
    Natarajan, Srinivasan
    Kim, Kimoon
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (52) : 16642 - 16648
  • [7] Beyond powders: Monoliths on the basis of metal-organic frameworks (MOFs)
    Qi, Xiaoyue
    Liu, Kexin
    Chang, Ziyong
    CHEMICAL ENGINEERING JOURNAL, 2022, 441
  • [8] Modeling gas separation in metal-organic frameworks
    Wells, Brad A.
    Chaffee, Alan L.
    ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2011, 17 (01): : 255 - 264
  • [9] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites
    Dinca, Mircea
    Long, Jeffrey R.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) : 6766 - 6779
  • [10] Manufacturing of metal-organic framework monoliths and their application in CO2 adsorption
    Hong, Wan Yun
    Perera, Semali P.
    Burrows, Andrew D.
    MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 214 : 149 - 155
12345