Multifunctional and Sustainable Fe-Iminopyridine Complexes for the Synthesis of Cyclic Carbonates

被引：30

作者：

Seong, Eun Young ^{[1
]}

Kim, Jae Hyung ^{[1
]}

Kim, Nam Hee ^{[1
]}

Ahn, Kwang-Hyun ^{[1
]}

Kang, Eun Joo ^{[1
]}

机构：

[1] Kyung Hee Univ, Dept Appl Chem, Yongin 17104, South Korea

来源：

CHEMSUSCHEM | 2019年 / 12卷 / 02期

基金：

新加坡国家研究基金会;

关键词：

carbon dioxide; cyclic carbonates; Fe-iminopyridine complex; homogeneous catalyst; hydrogen bond donor; ALUMINUM-SALEN CATALYSTS; ORGANIC CARBONATES; IONIC LIQUIDS; EFFICIENT CATALYSTS; CHEMICAL FIXATION; CO2; FIXATION; IRON(III) CATALYST; DIOXIDE FIXATION; HIGHLY EFFICIENT; EPOXIDES;

D O I：

10.1002/cssc.201802563

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of multifunctional and sustainable Fe catalysts for the formation of cyclic carbonates from epoxides and carbon dioxide at 80 degrees C and 3 bar pressure is presented. The optimal catalyst possesses a halide counteranion and a hydrogen bond donor to activate the epoxide for ring opening, affording a single-component, cocatalyst-free catalytic system.

引用

页码：409 / 415

页数：7

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