Halogen-Bond-Assisted Guest Inclusion in a Synthetic Cavity

被引：47
作者：
Takezawa, Hiroki [1 ]
Murase, Takashi [2 ]
Resnati, Giuseppe [3 ]
Metrangolo, Pierangelo [3 ]
Fujita, Makoto [1 ]
机构：
[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
[2] Yamagata Univ, Dept Mat & Biol Chem, Fac Sci, Yamagata, Yamagata 9908560, Japan
[3] Politecn Milan, Lab Nanostruct Fluorinated Mat NFMLab, Dept Chem Mat & Chem Engn Giulio Natta, I-20131 Milan, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 29期
关键词：
halocarbon compounds; halogen bonding; host-guest interactions; molecular recognition; self-assembly; HYDROGEN-BONDS; AB-INITIO; RECOGNITION; WATER; THERMODYNAMICS; COMPLEXES; GEOMETRY; NITROGEN; HOSTS;
D O I：
10.1002/anie.201500994
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The confined space inside a self-assembled cage enhanced halogen bonding (XB) between iodoperfluorocarbons (XB donors) and NO3- anions or H2O molecules (XB acceptors), as confirmed by NMR spectroscopy in solution and by X-ray crystallography in the solid state. The cavity also bound an XB donor-acceptor pair, C6F3I3 and C6H5NMe2, in a selective pairwise fashion.
引用
收藏
页码：8411 / 8414
页数：4
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