Electronic and vibrational circular dichroism spectroscopies for the understanding of chiral organization in porphyrin aggregates

被引:16
作者
Nieto-Ortega, Belen [1 ]
Ramirez, Francisco J. [1 ]
Amabilino, David B. [2 ]
Linares, Mathieu [3 ]
Beljonne, David [4 ]
Lopez Navarrete, Juan T. [1 ]
Casado, Juan [1 ]
机构
[1] Univ Malaga, Dept Quim Fis, E-29071 Malaga, Spain
[2] CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
[3] Linkoping Univ, Computat Phys IFM, S-58183 Linkoping, Sweden
[4] Univ Mons, B-7000 Mons, Belgium
关键词
SUPRAMOLECULAR CHIRALITY; RAMAN-SPECTROSCOPY; ASSEMBLIES; MOLECULES;
D O I
10.1039/c2cc34374f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dichroic optical spectroscopies and theoretical modelling have been used to describe the structure of aggregates of porphyrins in their gels in terms of: (i) the formation of helicoidal structures, (ii) the sign of the handedness, (iii) their extent and degree of structural order, and (iv) the annealing of the structural defects.
引用
收藏
页码:9147 / 9149
页数:3
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