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Electronic and vibrational circular dichroism spectroscopies for the understanding of chiral organization in porphyrin aggregates
被引:16
|作者:
Nieto-Ortega, Belen
[1
]
Ramirez, Francisco J.
[1
]
Amabilino, David B.
[2
]
Linares, Mathieu
[3
]
Beljonne, David
[4
]
Lopez Navarrete, Juan T.
[1
]
Casado, Juan
[1
]
机构:
[1] Univ Malaga, Dept Quim Fis, E-29071 Malaga, Spain
[2] CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
[3] Linkoping Univ, Computat Phys IFM, S-58183 Linkoping, Sweden
[4] Univ Mons, B-7000 Mons, Belgium
关键词:
SUPRAMOLECULAR CHIRALITY;
RAMAN-SPECTROSCOPY;
ASSEMBLIES;
MOLECULES;
D O I:
10.1039/c2cc34374f
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Dichroic optical spectroscopies and theoretical modelling have been used to describe the structure of aggregates of porphyrins in their gels in terms of: (i) the formation of helicoidal structures, (ii) the sign of the handedness, (iii) their extent and degree of structural order, and (iv) the annealing of the structural defects.
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页码:9147 / 9149
页数:3
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