Fabrication and evaluation of a dimension-reduction fiberoptic system for chemical imaging applications

被引:17
作者
Nelson, MP [1 ]
Myrick, ML [1 ]
机构
[1] Univ S Carolina, Dept Biochem & Chem, Columbia, SC 29208 USA
关键词
D O I
10.1063/1.1149804
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A novel system for rapid chemical imaging is described and evaluated. The system operates via single-frame spectroscopic chemical imaging with high spectroscopic resolution using a second-generation dimension-reduction fiberoptic array. Images are focused onto a rectangular array of square close-packed 25 mu m cross-sectional f/2 optical fibers that are drawn into a linear distal array with serpentine ordering. The distal end is then imaged with an f/2 spectrograph equipped with a holographic grating and a gated intensified charge-coupled device (ICCD) camera for analysis. Software is used to extract the spatial/spectral information contained in a single ICCD image and deconvolute it into wavelength-specific univariate reconstructed images or position-specific spectra that span an 86 nm wavelength space using our present grating. A description of the fabrication of the dimension-reduction array is given as well as a zero-order reconstruction of a binary target and single-wavelength image reconstructions of a laser-induced plasma. The system is evaluated for spatial and spectral resolution, throughput, image brightness, resolving power, depth of focus, and channel cross talk. Treatment of the spectroscopic data obtained from the ICCD images for use in potential chemical imaging applications is discussed. (C) 1999 American Institute of Physics. [S0034-6748(99)05106-0].
引用
收藏
页码:2836 / 2844
页数:9
相关论文
共 24 条
[1]   Monitoring anhydride and acid conversion in supercritical/hydrothermal water by in situ fiber-optic Raman spectroscopy [J].
Bell, WC ;
Booksh, KS ;
Myrick, ML .
ANALYTICAL CHEMISTRY, 1998, 70 (02) :332-339
[2]   AUTOMATED MICRO-RAMAN MAPPING AND IMAGING APPLIED TO SILICON DEVICES AND ZIRCONIA CERAMIC STRESS AND GRAIN-BOUNDARY MORPHOLOGY [J].
BOWDEN, M ;
DICKSON, GD ;
GARDINER, DJ ;
WOOD, DJ .
APPLIED SPECTROSCOPY, 1990, 44 (10) :1679-1684
[3]   Spectroscopic imaging of laser-induced plasma [J].
Bulatov, V ;
Xu, L ;
Schechter, I .
ANALYTICAL CHEMISTRY, 1996, 68 (17) :2966-2973
[4]  
COLIN J, 1994, APPL OPTICS, V33, P7520
[5]   RAMAN-SPECTROSCOPY WITH A LOW-COST IMAGING CCD ARRAY [J].
COOPER, JB ;
AUST, J ;
STELLMAN, C ;
CHIKE, K ;
MYRICK, ML ;
SCHWARTZ, R ;
LONGMIRE, M .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1994, 50 (03) :567-575
[6]   Multicomponent analysis of stripping voltammograms by target transformation factor analysis [J].
Gao, L ;
Ren, SX .
JOURNAL OF AUTOMATIC CHEMISTRY, 1996, 18 (05) :175-179
[7]   AUTOMATED MAPPING OF HIGH-TEMPERATURE CORROSION PRODUCTS ON IRON CHROMIUM-ALLOY USING RAMAN MICROSCOPY [J].
GARDINER, DJ ;
LITTLETON, CJ ;
BOWDEN, M .
APPLIED SPECTROSCOPY, 1988, 42 (01) :15-19
[8]   GENERALIZED RANK ANNIHILATION FACTOR-ANALYSIS, ITERATIVE TARGET TRANSFORMATION FACTOR-ANALYSIS, AND RESIDUAL BILINEARIZATION FOR THE QUANTITATIVE-ANALYSIS OF DATA FROM LIQUID-CHROMATOGRAPHY WITH PHOTODIODE ARRAY DETECTION [J].
GERRITSEN, MJP ;
TANIS, H ;
VANDEGINSTE, BGM ;
KATEMAN, G .
ANALYTICAL CHEMISTRY, 1992, 64 (18) :2042-2056
[9]   TARGET TRANSFORMATION FACTOR-ANALYSIS AS AN AEROSOL MASS APPORTIONMENT METHOD - A REVIEW AND SENSITIVITY STUDY [J].
HOPKE, PK .
ATMOSPHERIC ENVIRONMENT, 1988, 22 (09) :1777-1792
[10]  
Ingle Jr J. D., 1988, SPECTROCHEMICAL ANAL