Matrix isolation and cold diffusion of mass-selected CS2 center dot+ in neon: Infrared observation of the asymmetric stretch of CS2 center dot+ and CS2 center dot-

被引：17

作者：

Halasinski, TM ^{[1
]}

Godbout, JT ^{[1
]}

Allison, J ^{[1
]}

Leroi, GE ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 36期

关键词：

D O I：

10.1021/jp960862f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vibrational spectroscopic characterization of neon matrices in which mass-selected CS2.+ and CS.+ were deposited reveals absorptions due to (nu(3)) CS2.+ (1207.1 cm(-1)) and (nu(3)) CS2.- (1159.4 cm(-1)). The results are compared to previous CO2.+ studies from this laboratory [Godbout et al. J. Phys. Chem. 1996, 100, 2892]. We also report controlled annealing studies of the matrices in which clustering of ionic species with neutral molecules is observed.

引用

收藏

页码：14865 / 14871

页数：7

相关论文

共 32 条

[1] FTIR SPECTRA OF (HF)N SPECIES IN SOLID NEON [J].

ANDREWS, L ;

BONDYBEY, VE ;

ENGLISH, JH .

JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (08) :3452-3457

[2] SPECTROSCOPY AND RELAXATION OF CS2+ IN SOLID NE [J].

BONDYBEY, VE ;

ENGLISH, JH .

JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (07) :3098-3102

[3] THEORETICAL POTENTIAL-ENERGY FUNCTION AND ROVIBRONIC SPECTRUM OF CO2+(X2-PI-G) [J].

BROMMER, M ;

CHAMBAUD, G ;

REINSCH, EA ;

ROSMUS, P ;

SPIELFIEDEL, A ;

FEAUTRIER, N ;

WERNER, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :8070-8082

[4] VIBRONIC SPECTRUM OF THE CS-2(+) ION IN THE X 2-PI-G STATE [J].

BROMMER, M ;

ROSMUS, P .

CHEMICAL PHYSICS LETTERS, 1993, 206 (5-6) :540-546

[5] HIGH-RESOLUTION FOURIER-TRANSFORM INFRARED-SPECTRA (CS)-C-12-S-32, (CS)-C-12-S-3), (CS)-C-12-S-34, AND (CS)-C-13-S-32 [J].

BURKHOLDER, JB ;

LOVEJOY, ER ;

HAMMER, PD ;

HOWARD, CJ .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 124 (02) :450-457

[6] ON THE PHOTOPOLYMERIZATION OF CARBON-DISULFIDE [J].

CATALDO, F .

INORGANICA CHIMICA ACTA, 1995, 232 (1-2) :27-33

[7] QUANTITATIVE PREDICTION OF INFRARED-SPECTRA OF ISOLATED MOLECULAR-IONS AND RADICALS .1. CO+, CO2+, AND CS2+ [J].

CHIN, S ;

PERSON, WB .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (03) :553-559

[8] PHOTOPOLYMERIZATION OF CARBON-DISULFIDE YIELDS THE HIGH-PRESSURE-PHASE (CS2)(X) [J].

COLMAN, JJ ;

TROGLER, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (45) :11270-11277

[9] THE NONRESONANT 2-PHOTON ZERO KINETIC-ENERGY PHOTOELECTRON-SPECTRUM OF CS2 [J].

FISCHER, I ;

LOCHSCHMIDT, A ;

STROBEL, A ;

NIEDNERSCHATTEBURG, G ;

MULLERDETHLEFS, K ;

BONDYBEY, VE .

CHEMICAL PHYSICS LETTERS, 1993, 202 (06) :542-548

[10] THE MIDINFRARED AND NEAR-INFRARED SPECTRA OF WATER AND WATER DIMER ISOLATED IN SOLID NEON [J].

FORNEY, D ;

JACOX, ME ;

THOMPSON, WE .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1993, 157 (02) :479-493

← 1 2 3 4 →