Which Parameter is Governing for Aqueous Redox Flow Batteries with Organic Active Material?

被引:24
作者
Hofmann, Jonas D. [1 ,2 ]
Schroeder, Daniel [1 ,2 ]
机构
[1] Justus Liebig Univ Giessen, Inst Phys Chem, Heinrich Buff Ring 17, D-35392 Giessen, Germany
[2] Justus Liebig Univ Giessen, Ctr Mat Res LaMa, Heinrich Buff Ring 16, D-35392 Giessen, Germany
关键词
Electrochemical performance; Energy storage; Quinones; Redox flow batteries; Voltammetry; ELECTROANALYTICAL METHODS; REDUCTION POTENTIALS; ONE-ELECTRON; ELECTROCHEMISTRY; QUINONES; ANTHRAQUINONE; VOLTAMMETRY; MOLECULES; DENSITY;
D O I
10.1002/cite.201800162
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A multitude of factors contribute to the performance of redox flow batteries with organic active material. In this work, experimental and theoretical methods are elucidated to give information about the most important of these: redox potential, kinetic rate constant, diffusion constant, and solubility. They are found to be highly interdependent - especially for different solvents. By implication, novel organic active materials have to be analyzed jointly by chemists, materials scientists, and by reaction and process engineers to propel the redox flow battery as future energy storage device.
引用
收藏
页码:786 / 794
页数:9
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