Resonance-enhanced multiphoton ionization with circularly polarized light: chiral carbonyls

被引：36

作者：

Boesl, Ulrich ^{[1
]}

Bornschlegl, Alexander ^{[1
]}

Loge, Christoph ^{[1
]}

Titze, Katharina ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85748 Garching, Germany

来源：

ANALYTICAL AND BIOANALYTICAL CHEMISTRY | 2013年 / 405卷 / 22期

基金：

欧洲研究理事会;

关键词：

Chiral analysis; Mass spectrometry/inductively coupled plasma mass spectrometry; Laser spectroscopy; Spectroscopy/instrumentation; LASER MASS-SPECTROMETRY; PHOTOELECTRON ANGULAR-DISTRIBUTIONS; OPTICAL-ACTIVITY; BASIS-SETS; GAS-PHASE; DICHROISM; KETONES; EXCITATION; SPECTROSCOPY; ABSORPTION;

D O I：

10.1007/s00216-012-6666-3

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

An introduction to the principle and possibilities of the new method of circular dichroism laser mass spectrometry is given and its state of development is reviewed. This method allows enantiosensitive, mass-selective probing of chiral molecules. It is based on the combination of resonance-enhanced multiphoton ionization with circularly polarized light and specially modified time-of-flight mass spectrometry. As an example, application to carbonyls is presented.

引用

页码：6913 / 6924

页数：12

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